ChemInform Abstract: Palladium-Catalyzed Reactions in Industry. Part 4. First Palladium- Catalyzed Heck Reactions with Efficient Colloidal Catalyst Systems.

ChemInform ◽  
2010 ◽  
Vol 28 (1) ◽  
pp. no-no
Author(s):  
M. BELLER ◽  
H. FISCHER ◽  
K. KUEHLEIN ◽  
C.-P. REISINGER ◽  
W. A. HERRMANN
Keyword(s):  
Heck Reactions ◽  
Palladium Catalyzed ◽  
Catalyzed Reactions ◽  
Catalyst Systems

First palladium-catalyzed Heck reactions with efficient colloidal catalyst systems

1996 ◽  
Vol 520 (1-2) ◽  
pp. 257-259 ◽  
Author(s):  
Matthias Beller ◽  
Hartmut Fischer ◽  
Klaus Kühlein ◽  
C.-P. Reisinger ◽  
W.A. Herrmann
Keyword(s):  
Heck Reactions ◽  
Palladium Catalyzed ◽  
Catalyst Systems

scholarly journals Dimethylisosorbide (DMI) as a Bio-Derived Solvent for Pd-Catalyzed Cross-Coupling Reactions

Synlett ◽  
2018 ◽  
Vol 29 (17) ◽  
pp. 2293-2297 ◽  
Author(s):  
Allan Watson ◽  
Kirsty Wilson ◽  
Jane Murray ◽  
Helen Sneddon ◽  
Craig Jamieson
Keyword(s):  
Chemical Industry ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Heck Reactions ◽  
Bond Forming ◽  
Cross Coupling Reactions ◽  
Bond Forming Reactions ◽  
Palladium Catalyzed ◽  
Catalyzed Reactions

Palladium-catalyzed bond-forming reactions, such as the ­Suzuki–Miyaura and Mizoroki–Heck reactions, are some of the most broadly utilized reactions within the chemical industry. These reactions frequently employ hazardous solvents; however, to adhere to increasing sustainability pressures and restrictions regarding the use of such solvents, alternatives are highly sought after. Here we demonstrate the utility of dimethyl isosorbide (DMI) as a bio-derived solvent in several benchmark Pd-catalyzed reactions: Suzuki–Miyaura (13 examples, 62–100% yield), Mizoroki–Heck (13 examples, 47–91% yield), and Sonogashira (12 examples, 65–98% yield).

Palladium chemistry in recent porphyrin research

2004 ◽  
Vol 08 (01) ◽  
pp. 93-102 ◽  
Author(s):  
Jun-ichiro Setsune
Keyword(s):  
Supramolecular Assembly ◽  
Molecular Size ◽  
Sonogashira Coupling ◽  
Stille Coupling ◽  
Heck Reactions ◽  
Nano Scale ◽  
Recent Developments ◽  
Palladium Catalyzed ◽  
Palladium Chemistry ◽  
Catalyzed Reactions

Palladium-catalyzed reactions such as Sonogashira coupling, Suzuki coupling, Stille coupling, Heck reactions, and Glaser-Hey oxidation were used to construct porphyrin modules of nano-scale molecular size in recent years. Recent developments in the supramolecular assembly of porphyrins and Pd (II) and in the organopalladium complexes of various porphyrins are also summarized.

Aryl-Decarboxylation Reactions Catalyzed by Palladium: Scope and Mechanism

Synthesis ◽  
2019 ◽  
Vol 52 (03) ◽  
pp. 365-377 ◽  
Author(s):  
Ryan A. Daley ◽  
Joseph J. Topczewski
Keyword(s):  
Carboxylic Acids ◽  
Boronic Acid ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Heck Reactions ◽  
Cross Coupling Reactions ◽  
Related Family ◽  
Organometallic Precursor ◽  
Palladium Catalyzed ◽  
Catalyzed Reactions

Palladium-catalyzed cross-couplings and related reactions have enabled many transformations essential to the synthesis of pharmaceuticals, agrochemicals, and organic materials. A related family of reactions that have received less attention are decarboxylative functionalization reactions. These reactions replace the preformed organometallic precursor (e.g., boronic acid or organostannane) with inexpensive and readily available carboxylic acids for many palladium-catalyzed reactions. This review focuses on catalyzed reactions where the elementary decarboxylation step is thought to occur at a palladium center. This review does not include decarboxylative reactions where decarboxylation is thought to be facilitated by a second metal (copper or silver) and is specifically limited to (hetero)arenecarboxylic acids. This review includes a discussion of oxidative Heck reactions, protodecarboxylation reactions, and cross-coupling reactions among others.1 Introduction2 Oxidative Heck Reactions3 Protodecarboxylation Reactions4 Cross-Coupling Reactions5 Other Reactions6 Conclusion

Palladium-Catalyzed Intermolecular Acylative Heck Reactions with Imides as Acyl Electrophiles

2021 ◽  
Author(s):  
Abhishek A. Kadam ◽  
Tanner L. Metz ◽  
Colton M. David ◽  
Mason T. Koeritz ◽  
Levi M. Stanley
Keyword(s):  
Heck Reactions ◽  
Palladium Catalyzed
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