ChemInform Abstract: Mesoporous Titanosilicate Molecular Sieves Prepared at Ambient Temperature by Electrostatic (S+I-, S+X-I+) and Neutral (S°I. degree.) Assembly Pathways: A Comparison of Physical Properties and Catalytic Activity for Peroxide Oxidation

ChemInform ◽  
2010 ◽  
Vol 27 (52) ◽  
pp. no-no
Author(s):  
W. ZHANG ◽  
M. FROEBA ◽  
J. WANG ◽  
P. T. TANEV ◽  
J. WONG ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Physical Properties ◽  
Ambient Temperature ◽  
Molecular Sieves ◽  
Peroxide Oxidation ◽  
Assembly Pathways

Platinum Black Catalysts. I. Physical Properties and Catalytic Activity*

1930 ◽  
Vol 34 (4) ◽  
pp. 748-752 ◽  
Author(s):  
G. B. Taylor ◽  
G. B. Kistiakowsky ◽  
J. H. Perry
Keyword(s):  
Catalytic Activity ◽  
Physical Properties ◽  
Platinum Black

scholarly journals Brazilian gutta-percha points. Part II: thermal properties

2007 ◽  
Vol 21 (1) ◽  
pp. 29-34 ◽  
Author(s):  
Cláudio Maniglia-Ferreira ◽  
Eduardo Diogo Gurgel-Filho ◽  
João Batista Araújo Silva Jr ◽  
Regina Célia Monteiro de Paula ◽  
Judith Pessoa Andrade Feitosa ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Properties ◽  
Physical Properties ◽  
Ambient Temperature ◽  
Amorphous Phase ◽  
Thermal Behaviour ◽  
Chemical Structure ◽  
Scanning Calorimetry ◽  
Gutta Percha ◽  
Thermal Manipulation

This study was undertaken to explore the effect of heating on gutta-percha, analyzing the occurrence of endothermic peaks corresponding to the transformation that occurs in the crystalline structure of the polymer during thermal manipulation. This study also seeked to determine the temperature at which these peaks occur, causing a transformation from the beta- to the alpha-form, and from the alpha- to the amorphous phase. Eight nonstandardized gutta-percha points commercially available in Brazil (Konne, Tanari, Endopoint, Odous, Dentsply 0.04, Dentsply 0.06, Dentsply TP, Dentsply FM) and pure gutta-percha (control) were analysed using differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA). The transition temperatures were determined and analysed. With the exception of Dentsply 0.04 and Dentsply 0.06, the majority of the products showed thermal behaviour typical of beta-gutta-percha, with two endothermic peaks, exhibiting two crystalline transformations upon heating from ambient temperature to 130°. Upon cooling and reheating, few samples presented two endothermic peaks. It was concluded that heating dental gutta-percha to 130°C causes changes to its chemical structure which permanently alter its physical properties.

Catalytic oxidation of diorganosilanes to 1,1,3,3-tetraorganodisiloxanes with gold nanoparticle assembly at the water–chloroform interface

2019 ◽  
Vol 43 (2) ◽  
pp. 813-819 ◽  
Author(s):  
Ravi Shankar ◽  
Asmita Sharma ◽  
Bhawana Jangir ◽  
Manchal Chaudhary ◽  
Gabriele Kociok-Köhn
Keyword(s):  
Catalytic Activity ◽  
Ambient Temperature ◽  
Catalytic Oxidation ◽  
Gold Nanoparticle ◽  
Photothermal Effect ◽  
Nanoparticle Assembly

The synthesis of 1,1,3,3-tetraorganodisiloxanes from the hydrolytic oxidation of diorganosilanes, RR1SiH2, using AuNPs as an interfacial catalyst is described. This study provides a manifestation of the photothermal effect in enhancing the catalytic activity at ambient temperature.

Synthesis, characterization and catalytic activity of actinide Th-MCM-41 and U-MCM-41 hexagonal packed mesoporous molecular sieves

2001 ◽  
Vol 171 (1-2) ◽  
pp. 229-241 ◽  
Author(s):  
Rodica Tismaneanu ◽  
Biswajit Ray ◽  
Rafael Khalfin ◽  
Rafi Semiat ◽  
Moris S. Eisen
Keyword(s):  
Catalytic Activity ◽  
Molecular Sieves ◽  
Mesoporous Molecular Sieves ◽  
Mcm 41

Facile fabrication of a heterogeneous Co-modified pyridinecarboxaldehyde-polyethylenimine catalyst for efficient CO2 conversion under mild conditions

2020 ◽  
Vol 7 (5) ◽  
pp. 1140-1147
Author(s):  
Chao Liu ◽  
Li Yang ◽  
Jiaxu Zhang ◽  
Jianmin Sun
Keyword(s):  
Catalytic Activity ◽  
Ambient Temperature ◽  
High Catalytic Activity ◽  
Co2 Conversion ◽  
Mild Conditions ◽  
Active Metal ◽  
Facile Fabrication ◽  
Amine Groups

A heterogeneous Co-modified pyridinecarboxaldehyde-polyethylenimine catalyst with active metal sites and amine groups exhibited high catalytic activity for CO2 conversion under mild conditions, even at ambient temperature.

scholarly journals Ambient Temperature CO Oxidation Using Palladium–Platinum Bimetallic Catalysts Supported on Tin Oxide/Alumina

Catalysts ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1223
Author(s):  
James K. Aldridge ◽  
Louise R. Smith ◽  
David J. Morgan ◽  
Albert F. Carley ◽  
Mandy Humphreys ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ambient Temperature ◽  
Co Oxidation ◽  
Tin Oxide ◽  
Photoelectron Spectroscopy ◽  
Bimetallic Catalysts ◽  
Moisture Resistance ◽  
X Ray ◽  
Sodium Stannate ◽  
Palladium Platinum

A series of Pt-based catalysts were synthesised and investigated for ambient temperature CO oxidation with the aim to increase catalytic activity and improve moisture resistance through support modification. Initially, bimetallic PtPd catalysts supported on alumina were found to exhibit superior catalytic activity compared with their monometallic counterparts for the reaction. Following an investigation into the effect of Pt/Pd ratio, a composition of 0.1% Pt/0.4% Pd was selected for further studies. Following this, SnO2/Al2O3 supports were synthesised from a variety of tin oxide sources. Catalytic activity was improved using sodium stannate and tin oxalate precursors compared with a traditional tin oxide slurry. Catalytic activity versus tin concentration was found to vary significantly across the three precursors, which was subsequently investigated by X-ray photoelectron spectroscopy (XPS) and energy-dispersive X-ray spectroscopy (EDX).

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