ChemInform Abstract: Active Thin Film Anodes for Alkaline Water Electrolysis.

ChemInform ◽  
2010 ◽  
Vol 27 (19) ◽  
pp. no-no
Author(s):  
R. N. SINGH
Keyword(s):  
Thin Film ◽  
Water Electrolysis ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water

scholarly journals Active IrO2 and NiO Thin Films Prepared by Atomic Layer Deposition for Oxygen Evolution Reaction

Catalysts ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 92 ◽  
Author(s):  
DJ Donn Matienzo ◽  
Daniel Settipani ◽  
Emanuele Instuli ◽  
Tanja Kallio
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Atomic Layer Deposition ◽  
Chemical Vapor ◽  
Water Electrolysis ◽  
Atomic Layer ◽  
Alkaline Water Electrolysis ◽  
Catalytic Systems ◽  
Alkaline Water ◽  
Layer Deposition

Atomic layer deposition (ALD) is a special type of chemical vapor deposition (CVD) technique that can grow uniformed thin films on a substrate through alternate self-limiting surface reactions. Recently, the application of these thin film materials to catalytic systems has begun to attract much attention, and the capacity to deposit these catalytic films in a highly controlled manner continues to gain importance. In this study, IrO2 and NiO thin films (approximately 25 to 60 nm) were deposited on industrial Ni expanded mesh as an anode for alkaline water electrolysis. Different ALD operating parameters such as the total number of deposition cycles, sublimation and deposition temperatures, and precursors pulse and purge lengths were varied to determine their effects on the structure and the electrochemical performance of the thin film materials. Results from the electrochemical tests (6 M KOH, 80 °C, up to 10 kA/m2) showed the catalytic activity of the samples. Oxygen overpotential values (ηO2) were 20 to 60 mV lower than the bare Ni expanded mesh. In summary, the study has demonstrated the feasibility of using the ALD technique to deposit uniformed and electroactive thin films on industrial metallic substrates as anodes for alkaline water electrolysis.

Phase transformation of the brownmillerite SrCoO2.5 thin film through alkaline water electrolysis

2014 ◽  
Vol 64 (12) ◽  
pp. 1845-1848 ◽  
Author(s):  
Octolia Togibasa Tambunan ◽  
Min Young Lee ◽  
Deok Hyeon Kim ◽  
Kadek Juliana Parwanta ◽  
Chang Uk Jung
Keyword(s):  
Thin Film ◽  
Phase Transformation ◽  
Water Electrolysis ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water

scholarly journals Erratum to: Phase transformation of the brownmillerite SrCoO2.5 thin film through alkaline water electrolysis

2014 ◽  
Vol 65 (4) ◽  
pp. 572-572
Author(s):  
Octolia Togibasa Tambunan ◽  
Min Young Lee ◽  
Deok Hyeon Kim ◽  
Kadek Juliana Parwanta ◽  
Chang Uk Jung
Keyword(s):  
Thin Film ◽  
Phase Transformation ◽  
Water Electrolysis ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water

Modelling and control of an alkaline water electrolysis process

2018 ◽  
Vol 1 (2) ◽  
pp. 9-14
Author(s):  
Marisol Cervantes-Bobadilla ◽  
Ricardo Fabricio Escobar Jiménez ◽  
José Francisco Gómez Aguilar ◽  
Tomas Emmanuel Higareda Pliego ◽  
Alberto Armando Alvares Gallegos
Keyword(s):  
Process Model ◽  
Water Electrolysis ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water ◽  
Electrolysis Process ◽  
Linear Dynamic ◽  
Energy Current ◽  
Identification Technique ◽  
Nonlinear Static ◽  
And Control

In this research, an alkaline water electrolysis process is modelled. The electrochemical electrolysis is carried out in an electrolyzer composed of 12 series-connected steel cells with a solution 30% wt of potassium hydroxide. The electrolysis process model was developed using a nonlinear identification technique based on the Hammerstein structure. This structure consists of a nonlinear static block and a linear dynamic block. In this work, the nonlinear static function is modelled by a polynomial approximation equation, and the linear dynamic is modelled using the ARX structure. To control the current feed to the electrolyzer an unconstraint predictive controller was implemented, once the unconstrained MPC was simulated, some restrictions are proposed to design a constrained MPC (CMPC). The CMPC aim is to reduce the electrolyzer's energy consumption (power supply current). Simulation results showed the advantages of using the CMPC since the energy (current) overshoots are avoided.

scholarly journals Boosting alkaline water electrolysis by asymmetric temperature modulation

2021 ◽  
Vol 119 (1) ◽  
pp. 013901
Author(s):  
Qinpeng Zhu ◽  
Peihua Yang ◽  
Tao Zhang ◽  
Zehua Yu ◽  
Kang Liu ◽  
...  
Keyword(s):  
Water Electrolysis ◽  
Temperature Modulation ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water

scholarly journals Towards the Hydrogen Economy—A Review of the Parameters That Influence the Efficiency of Alkaline Water Electrolyzers

Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3193
Author(s):  
Ana L. Santos ◽  
Maria-João Cebola ◽  
Diogo M. F. Santos
Keyword(s):  
Energy Content ◽  
Water Electrolysis ◽  
High Energy ◽  
Operating Conditions ◽  
Energy Sources ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water ◽  
New Energy ◽  
Recent Developments ◽  
Cell Components

Environmental issues make the quest for better and cleaner energy sources a priority. Worldwide, researchers and companies are continuously working on this matter, taking one of two approaches: either finding new energy sources or improving the efficiency of existing ones. Hydrogen is a well-known energy carrier due to its high energy content, but a somewhat elusive one for being a gas with low molecular weight. This review examines the current electrolysis processes for obtaining hydrogen, with an emphasis on alkaline water electrolysis. This process is far from being new, but research shows that there is still plenty of room for improvement. The efficiency of an electrolyzer mainly relates to the overpotential and resistances in the cell. This work shows that the path to better electrolyzer efficiency is through the optimization of the cell components and operating conditions. Following a brief introduction to the thermodynamics and kinetics of water electrolysis, the most recent developments on several parameters (e.g., electrocatalysts, electrolyte composition, separator, interelectrode distance) are highlighted.

scholarly journals Electrode-diaphragm assembly for alkaline water electrolysis

2020 ◽  
Vol 1683 ◽  
pp. 052011
Author(s):  
V N Kuleshov ◽  
S V Kurochkin ◽  
N V Kuleshov ◽  
D V Blinov ◽  
O Y Grigorieva
Keyword(s):  
Water Electrolysis ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water
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