ChemInform Abstract: Hydride Formation in Two-Phase (Ti3Al + TiAl) Titanium Aluminides During Cathodic Charging and Its Dissociation.

ChemInform ◽  
2010 ◽  
Vol 26 (15) ◽  
pp. no-no
Author(s):  
A. TAKASAKI ◽  
K. OJIMA ◽  
Y. TANEDA
Keyword(s):  
Titanium Aluminides ◽  
Two Phase ◽  
Hydride Formation ◽  
Cathodic Charging

Hot work processing, microstrructure and mechanical properties of two-phase γ titanium aluminides

1994 ◽  
Vol 185 (1-2) ◽  
pp. 17-24 ◽  
Author(s):  
X.D. Zhang ◽  
R.V. Ramanujan ◽  
T.A. Dean ◽  
M.H. Loretto
Keyword(s):  
Mechanical Properties ◽  
Titanium Aluminides ◽  
Two Phase

Microstructural Characterization of α2 + γ Titanium Aluminides

1997 ◽  
Vol 3 (S2) ◽  
pp. 701-702
Author(s):  
D. J. Larson ◽  
M. K. Miller
Keyword(s):  
Titanium Aluminides ◽  
Base Alloy ◽  
Significant Proportion ◽  
Weight Ratio ◽  
High Strength ◽  
Microstructural Characterization ◽  
Two Phase ◽  
Tial Alloys ◽  
Boron Doped

Two-phase α2+γ TiAl alloys with microalloying additions, Fig. 1, are of interest due to the high strength-to-weight ratio they can provide in automotive and aircraft applications. In boron-doped α2+γTiAl containing Cr, Nb, and W, the B levels were found to be significantly depleted below the nominal alloy content in both the α2 andγ phases. The boron solubilities in the γ and α2 phases were 0.011 ± 0.005 at. % B and 0.003 ± 0.005 at. % B, respectively in Ti-47% Al-2% Cr-1.8% Nb-0.2% W-0.15 % B that was aged for 2 h at 900°C (base alloy). The majority of the B was in a variety of borides including TiB, TiB2 and a Cr-enriched (Ti,Cr)2B precipitate. With the exception of the smaller (< 50 nm thick) Cr-enriched (Ti,Cr)2B precipitates, Fig. 2, most of the borides were larger than ∼100 nm. A significant proportion of the microalloying additions is in these borides, Table 1.

Elemental Segregation and O-Phase Formation in a Gamma-TiAl Alloy

2018 ◽  
Vol 941 ◽  
pp. 741-746 ◽  
Author(s):  
Heike Gabrisch ◽  
Tobias Krekeler ◽  
Uwe Lorenz ◽  
Marcus Willi Rackel ◽  
Martin Ritter ◽  
...  
Keyword(s):  
Tial Alloy ◽  
Titanium Aluminides ◽  
Orthorhombic Phase ◽  
Aircraft Engines ◽  
Duplex Microstructure ◽  
Two Phase ◽  
Chemical Homogeneity ◽  
Phase Form ◽  
Tial Alloys ◽  
O Phase

Titanium aluminides based on the L10 ordered g-phase are promising structural light-weight materials for applications in aircraft engines. Typical compositions for γ-TiAl alloys lie in the range Ti-(44-48)Al (at.-%). For high creep resistance, a two-phase microstructure based on lamellar (α2+γ)-colonies is desirable that may be tuned towards better ductility by introducing pure γ-grains (near lamellar or duplex microstructure).γ-TiAl alloys are often alloyed with niobium for increased oxidation resistance and improved mechanical properties. HEXRD and TEM studies of the alloy Ti-42Al-8.5Nb revealed that the orthorhombic O-phase forms during annealing at 500-650°C. This orthorhombic phase has been known in Nb-rich, Al-lean, α2-based Ti-aluminides since the late 1980ies (Nb> 12.5 at.-%, Al< 31 at.-%) but the finding in γ-based alloys is new.TEM imaging showed that the O-phase is located within α2 lamellae of lamellar (α2+γ)-colonies. O-phase domains and α2 phase form small columnar crystallites based in the α2/γ interface. The columnar crystallites grow parallel to the [0001] direction of the α2 phase and appear as facets when observed along this direction. The evolution of domains and facets with annealing time and the chemical homogeneity of the phases are investigated.The results of STEM imaging show that O-phase domains form during annealing at 550 °C for 8hours or 168 hours. After 168 hours of annealing Nb segregations are observed by EDX mapping within O-phase domains. In comparison, no segregation of niobium is detected after 8 hours of annealing.

scholarly journals Hydride Formation at Cathodic Charging of α-Ti

2008 ◽  
Vol 8 (1) ◽  
Author(s):  
E. Łunarska ◽  
O. Chernyayeva ◽  
D. Lisovytskiy
Keyword(s):  
Hydride Formation ◽  
Cathodic Charging

Microstructure and Deformation of Ti-22Al-23Nb Orthorhombic-Based Monolithic and Composite Titanium Aluminides

1994 ◽  
Vol 350 ◽  
Author(s):  
François-charles dary ◽  
Shiela R. Woodard ◽  
Tresa M. Pollock
Keyword(s):  
High Temperature ◽  
Titanium Aluminides ◽  
Matrix Composites ◽  
Low Oxygen ◽  
Microstructural Stability ◽  
Two Phase ◽  
Intermetallic Matrix ◽  
Three Phase ◽  
Intermetallic Matrix Composites ◽  
Temperature Exposure

AbstractA new class of intermetallic matrix composites (IMC's) based on orthorhombic titanium aluminides offer attractive properties for high-temperature structural components at temperatures up to 760°C. Results from an ongoing study on the microstructural stability and mechanical properties of the orthorhombic-based alloy Ti-22Al–23Nb (at%), in both monolithic and composite forms, are discussed. Oxygen acquired during processing or as a result of high-temperature exposure in air or vacuum has a pronounced influence on the microstructure of the monolithic and composite materials. Two-phase lath microstructures of ordered beta (βo) + orthorhombic (O) phases produced by processing low oxygen material above the beta transus are morphologically stable at 760°C. Conversely, in higher-oxygen three-phase microstructures containing O+βo+ α2(Ti3Al), lath coarsening and additional precipitation of α2 in oxygen-enriched sheet surface regions is observed. At 760°C/69MPa the two-phase lath microstructure has a higher creep resistance and lower tensile strength compared to the three-phase α2- containing microstructures of the higher oxygen material.

Interface Related Strength Phenomena in Two-Phase Titanium Aluminides

1999 ◽  
Vol 586 ◽  
Author(s):  
U. Christoph ◽  
M. Oehring ◽  
F. Appel
Keyword(s):  
Crystal Structure ◽  
Electron Microscope ◽  
Microscope Study ◽  
Lamellar Structure ◽  
Electron Microscope Study ◽  
Titanium Aluminides ◽  
Intermetallic Phases ◽  
Dislocation Loops ◽  
Two Phase ◽  
Interfacial Dislocations

ABSTRACTPhase equilibria and transformations in near-equiatomic titanium aluminides lead to the formation of a lamellar structure comprising of the intermetallic phases α2(Ti3Al) and γ(TiAl). Due to the differences in lattice parameters and crystal structure, coherency stresses and mismatch structures occur at various types of semicoherent interfaces present in the material. The present paper reports an electron microscope study of the atomic structure of the interfaces. The residual coherency stresses present at the interfaces were determined by analysing the curvature of dislocation loops which were emitted from the network of interfacial dislocations. The implication of these stresses on creep will be discussed.

Site Occupancy Determination by ALCHEMI of Nb and Cr in γ-TiAl and Their Effects on the a to γ Massive Phase Transformation

1999 ◽  
Vol 589 ◽  
Author(s):  
T.M. Miller ◽  
L. Wang ◽  
W.H. Hofmeister ◽  
J.E. Wittig ◽  
I.M. Anderson
Keyword(s):  
Solid State ◽  
Rapid Solidification ◽  
Titanium Aluminides ◽  
Site Occupancy ◽  
Solidification Structure ◽  
Two Phase ◽  
Alloying Additions ◽  
Massive Phase ◽  
Ternary Alloying ◽  
Solid State Cooling

AbstractAtom location by channeling enhanced microanalysis (ALCHEMI) has been used to characterize the site distributions of Nb and Cr alloying additions in the L10-ordered γ phase of ternary titanium aluminides. Two alloys, Ti50Al48Cr2 and Ti50A148Nb2, were processed by furnace cooling from 1300°C (within the α-γ two phase field) as well as by rapid solidification using twin-anvil splat quenching of electromagnetically levitated and undercooled samples. ALCHEMI studies of furnace cooled samples yield results generally consistent with those in the published literature. Nb alloying additions are found to partition exclusively to the ‘Ti’ sublattice, while Cr alloying additions exhibit an ‘Al‘ sublattice preference. However, a higher degree of disorder can be achieved with rapid solidification and high solid state cooling rates (105-106 K/s). Significant distribution of the ternary elements between the ‘Ti’ and ‘Al‘ sublattices has been measured in the splat quenched samples, with up to 12% of the Nb atoms occupying the ‘Al‘ sublattice and the fraction of Cr atoms on the ‘Ti’ sublattice doubling to ∼30%. Rapid solidification of TiAl produces an equiaxed hexagonal α phase solidification structure that transforms in a massive fashion to the tetragonal γ phase. Although the amount of massively transformed γ is dependent upon the solid state cooling rate, ternary alloying additions can more strongly influence the transformation kinetics. The Nb-modified alloy exhibits significant amounts of the massively tranformed γ, similar to the Ti52Al48 binary alloy, whereas little massively transformed γ is observed in the Cr-modified alloy. These results can be correlated with the relative atomic size, lattice distortion, and sublattice site occupancy of Nb and Cr in the L10 unit cell.

Twinning in Crack Tip Plasticity of Two-Phase Titanium Aluminides

2000 ◽  
Vol 646 ◽  
Author(s):  
Fritz Appel
Keyword(s):  
Titanium Aluminide ◽  
Titanium Aluminides ◽  
Crack Tip ◽  
High Resolution Electron Microscopy ◽  
Strength Properties ◽  
Mechanical Twinning ◽  
Atomic Scale ◽  
Two Phase ◽  
Design Concepts ◽  
Crack Tip Plasticity

ABSTRACTIntermetallic titanium aluminides based on γ(TiAl) are prone to cleavage fracture on low index lattice planes. Unfavourably oriented grains may therefore provide easy crack paths so that the cracks can rapidly grow to a length which is critical for failure. The effect of crack tip plasticity on crack propagation in γ(TiAl) was investigated by conventional and high-resolution electron microscopy. Crack tip shielding due to mechanical twinning was recognized as toughening mechanism, which occur at the atomic scale and apparently is capable to stabilize fastly growing cracks. The potential of the mechanism will be discussed in the context of novel design concepts for improving the strength properties of γ-base titanium aluminide alloys.

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