ChemInform Abstract: Conformational Analysis of 2-Chloro-2-fluoroacetaldehyde and Calculated Transition State Structures of Nucleophilic Addition Reactions.

ChemInform ◽  
2010 ◽  
Vol 26 (10) ◽  
pp. no-no
Author(s):  
G. FRENKING ◽  
K. F. KOEHLER ◽  
M. T. REETZ
Keyword(s):  
Transition State ◽  
Conformational Analysis ◽  
Nucleophilic Addition ◽  
Addition Reactions ◽  
Transition State Structures

The reliability of MINDO method for characterizing the transition state structures in radical addition reactions

1982 ◽  
Vol 47 (3) ◽  
pp. 802-808 ◽  
Author(s):  
Robert Ponec ◽  
Jaroslav Málek
Keyword(s):  
Hydrogen Atom ◽  
Transition State ◽  
Ab Initio ◽  
Radical Addition ◽  
Addition Reactions ◽  
Methyl Radical ◽  
Transition State Structures

The additions of the methyl radical and hydrogen atom to ethylene were chosen to test the reliability of MINDO method for predicting the transition state structures. It has been shown that the structures obtained at the level of the MINDO method differ markedly from the ab initio calculated structures.

scholarly journals Stereoselective nucleophilic addition reactions to cyclic N-acyliminium ions using the indirect cation pool method: Elucidation of stereoselectivity by spectroscopic conformational analysis and DFT calculations

2018 ◽  
Vol 14 ◽  
pp. 1192-1202 ◽  
Author(s):  
Koichi Mitsudo ◽  
Junya Yamamoto ◽  
Tomoya Akagi ◽  
Atsuhiro Yamashita ◽  
Masahiro Haisa ◽  
...  
Keyword(s):  
Low Temperature ◽  
Dft Calculations ◽  
Conformational Analysis ◽  
Nucleophilic Addition ◽  
Addition Reactions ◽  
Acyliminium Ions

In this study, six-membered N-acyliminium ions were generated by the “indirect cation pool” method and reacted with several nucleophiles. These reactions afforded disubstituted piperidine derivatives with high diastereoselectivities and good to excellent yields. The conformations of the obtained N-acyliminium ions were studied by low temperature NMR analyses and DFT calculations and were found to be consistent with the Steven’s hypothesis.

scholarly journals Nucleophilic Addition Reactions of Nitriles to Nitrones under Mild Silylation Conditions

Synlett ◽  
2014 ◽  
Vol 25 (13) ◽  
pp. 1863-1868 ◽  
Author(s):  
Fumihiko Yoshimura ◽  
Keiji Tanino ◽  
Taiki Abe
Keyword(s):  
Nucleophilic Addition ◽  
Addition Reactions
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