ChemInform Abstract: The Methyl-Transfer Reaction in Crystalline Methyl 2-(Methylthio) benzenesulfonate: A Thermally Induced Non-Topochemical Solid-State Reaction

ChemInform ◽  
2010 ◽  
Vol 22 (29) ◽  
pp. no-no
Author(s):  
P. VENUGOPALAN ◽  
K. VENKATESAN ◽  
J. KLAUSEN ◽  
E. NOVOTNY-BREGGER ◽  
C. LEUMANN ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Transfer Reaction ◽  
Thermally Induced ◽  
Methyl Transfer

On the Methyl-Transfer Reaction in Crystalline Methyl 2-(Methylthio)benzenesulfonate: a Thermally Induced Non-Topochemical Solid-State Reaction

1991 ◽  
Vol 74 (3) ◽  
pp. 662-669 ◽  
Author(s):  
P. Venugopalan ◽  
K. Venkatesan ◽  
J�rg Klausen ◽  
Elisabeth Novotny-Bregger ◽  
Christian Leumann ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Transfer Reaction ◽  
Thermally Induced ◽  
Methyl Transfer

Thermally induced electron transfer reaction of heterometallic dinuclear complex in the solid state

Polyhedron ◽  
1996 ◽  
Vol 15 (3) ◽  
pp. 415-420 ◽  
Author(s):  
Parimal Kundu ◽  
Manas Kumar Saha ◽  
Sutapa Sen ◽  
Samiran Mitra ◽  
Sanjay Kumar ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Solid State ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Dinuclear Complex ◽  
Thermally Induced

The wustite-spinel interface

1987 ◽  
Vol 45 ◽  
pp. 268-269
Author(s):  
S.R. Summerfelt ◽  
C.B. Carter
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Strain Energy ◽  
Matrix Material ◽  
Lattice Misfit ◽  
Solid State Reactions ◽  
Oxygen Sublattice ◽  
Large Particles ◽  
Small Lattice ◽  
Coherent Interfaces

The wustite-spinel interface can be viewed as a model interface because the wustite and spinel can share a common f.c.c. oxygen sublattice such that only the cations distribution changes on crossing the interface. In this study, the interface has been formed by a solid state reaction involving either external or internal oxidation. In systems with very small lattice misfit, very large particles (>lμm) with coherent interfaces have been observed. Previously, the wustite-spinel interface had been observed to facet on {111} planes for MgFe2C4 and along {100} planes for MgAl2C4 and MgCr2O4, the spinel then grows preferentially in the <001> direction. Reasons for these experimental observations have been discussed by Henriksen and Kingery by considering the strain energy. The point-defect chemistry of such solid state reactions has been examined by Schmalzried. Although MgO has been the principal matrix material examined, others such as NiO have also been studied.

Observation of solid-state reaction between a thin yttria film and a (0001) α-alumina substrate

1994 ◽  
Vol 52 ◽  
pp. 644-645
Author(s):  
J. R. Heffelfinger ◽  
C. B. Carter
Keyword(s):  
Electron Microscopy ◽  
Solid State ◽  
Solid State Reaction ◽  
Yttrium Aluminum Garnet ◽  
Secondary Phase ◽  
Ceramic Composites ◽  
Alumina Substrate ◽  
Transmission Electron ◽  
Alumina Fibers ◽  
Optical Applications

Transmission-electron microscopy (TEM), scanning-electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS) were used to investigate the solid-state reaction between a thin yttria film and a (0001) α-alumina substrate. Systems containing Y2O3 (yttria) and Al2O3 (alumina) are seen in many technologically relevant applications. For example, yttria is being explored as a coating material for alumina fibers for metal-ceramic composites. The coating serves as a diffusion barrier and protects the alumina fiber from reacting with the metal matrix. With sufficient time and temperature, yttria in contact with alumina will react to form one or a combination of phases shown by the phase diagram in Figure l. Of the reaction phases, yttrium aluminum garnet (YAG) is used as a material for lasers and other optical applications. In a different application, YAG is formed as a secondary phase in the sintering of AIN. Yttria is added to AIN as a sintering aid and acts as an oxygen getter by reacting with the alumina in AIN to form YAG.

PREDICTION OF GLASS FORMATION BY SOLID STATE REACTION IN ALLOYS

1990 ◽  
Vol 51 (C4) ◽  
pp. C4-111-C4-117 ◽  
Author(s):  
L. J. GALLEGO ◽  
J. A. SOMOZA ◽  
H. M. FERNANDEZ ◽  
J. A. ALONSO
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Glass Formation
Sign in / Sign up

Export Citation Format

Share Document