ChemInform Abstract: Homolytic Addition Reaction of Dimethyl Phosphite with O- and N-Allyl Derivatives of N′-Phenylcarbamic Acid.

ChemInform ◽  
1990 ◽  
Vol 21 (47) ◽  
Author(s):  
A. I. RAKHIMOV ◽  
B. L. RYSIN
Keyword(s):  
Addition Reaction ◽  
Homolytic Addition ◽  
Dimethyl Phosphite ◽  
Derivatives Of

A Novel Migrative Addition Reaction of Hydrazines to the Diketone Derivatives of C60.

ChemInform ◽  
2003 ◽  
Vol 34 (34) ◽  
Author(s):  
Sho-ichi Iwamatsu ◽  
Fumiaki Ono ◽  
Shizuaki Murata
Keyword(s):  
Addition Reaction ◽  
Derivatives Of

ChemInform Abstract: Addition Reaction of Dimethyl Phosphite with 1-Phenyl-1-butyn-3-one.

ChemInform ◽  
1990 ◽  
Vol 21 (13) ◽  
Author(s):  
B. U. MINBAEV ◽  
N. I. YASHNOVA ◽  
B. D. ABIYUROV
Keyword(s):  
Addition Reaction ◽  
Dimethyl Phosphite

ChemInform Abstract: Homolytic Addition Reaction of Benzyl Bromide with Unsaturated Compounds Initiated by Metal Complexes.

ChemInform ◽  
2010 ◽  
Vol 25 (26) ◽  
pp. no-no
Author(s):  
T. T. VASIL'EVA ◽  
S. I. GAPUSENKO ◽  
S. V. VITT ◽  
A. B. TERENT'EV
Keyword(s):  
Metal Complexes ◽  
Addition Reaction ◽  
Benzyl Bromide ◽  
Homolytic Addition ◽  
Unsaturated Compounds

scholarly journals 1H and 13C Nuclear Magnetic Resonance Spectroscopy of Some Derivatives of Nitro Sugars

1973 ◽  
Vol 51 (11) ◽  
pp. 1797-1800 ◽  
Author(s):  
N. Gurudata ◽  
F. J. M. Rajabalee
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Chemical Shift ◽  
Magnetic Resonance Spectroscopy ◽  
Nuclear Magnetic Resonance Spectroscopy ◽  
Addition Reaction ◽  
Chemical Shifts ◽  
Resonance Spectroscopy ◽  
13C Nuclear Magnetic Resonance ◽  
Derivatives Of

Eight 2,3-dideoxy-2-amino-3-nitrosugar derivatives have been obtained by an elimination–addition reaction on the α and β anomers of methyl-4,6-O-benzylidene-3-deoxy-3-nitro-glucopyranoside-2-acetate. P.m.r. is used to show that the compounds exist in the CE conformation. 13C.m.r. data are presented for three anomeric pairs. Trends in the C-13 chemical shifts are found to be similar to those reported in other studies of carbohydrates. Exceptions in direction and magnitude of chemical shift differences are discussed.

Topochemische Reaktionen von Monomeren mit konjugierten Dreifachbindungen / Tochemical Reactions of Monomers with conjugated triple Bonds

1969 ◽  
Vol 24 (7) ◽  
pp. 824-832 ◽  
Author(s):  
Gerhard Wegner
Keyword(s):  
Solid State ◽  
Addition Reaction ◽  
Kcal Mole ◽  
Triple Bonds ◽  
Qualitative Survey ◽  
Polymer Formation ◽  
Functional Derivatives ◽  
Solid State Polymerization ◽  
Topotactic Reaction ◽  
Derivatives Of

The solid-state polymerization of functional derivatives of 2,4-hexadiin-1,6-diol caused by light or by heat was investigated. A qualitative survey demonstrates that the presence of groups capable of hydrogen-bonding are one of the most important factors for solid-state reactivity of conjugated triple-bonds. Compounds which do not form hydrogen-bonds were unreactive in most cases. Urethanes were the most reactive class of derivatives, 2,4-hexadiin-1,6-diol-bis-phenylurethane giving the best results. The relation and the reactivity of several modifications of this compound are described. Heating of one modification of 2,4-hexadiin-1,6-diol-bis-phenylurethane at temperatures between 70 and 120°C yielded in a topotactic reaction highly crystalline fibres of a coppercoloured polymer. Time-conversion studies were made and the activation energy of the polymerization determined to 19 kcal/mole. The mechanism of polymer-formation is discussed. It is highly probable that poly-1,4-bis-phenylcarbamoyloxymethyl-trans-butatrien, a polymer with three cumulated double-bonds per repeating-unit, is formed by a 1,4-addition reaction.

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