ChemInform Abstract: New Applications of Organopalladium Compounds in Organic Synthesis

ChemInform ◽  
1990 ◽  
Vol 21 (40) ◽  
Author(s):  
R. C. LAROCK
Keyword(s):  
Organic Synthesis ◽  
New Applications

Electrochemical Oxidative Esterification of Thiophenols: Efficient Access to Sulfinic Esters

2020 ◽  
Vol 17 (7) ◽  
pp. 540-547
Author(s):  
Chun-Hui Yang ◽  
Cheng Wu ◽  
Jun-Ming Zhang ◽  
Xiang-Zhang Tao ◽  
Jun Xu ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Efficient Method ◽  
High Efficiency ◽  
Building Blocks ◽  
Constant Current ◽  
Good Efficiency ◽  
Oxidative Esterification ◽  
Efficient Access ◽  
New Applications ◽  
Sulfinic Esters

Background: The sulfinic esters are important and useful building blocks in organic synthesis. Objective: The aim of this study was to develop a simple and efficient method for the synthesis of sulfinic esters. Materials and Methods: Constant current electrolysis from thiols and alcohols was selected as the method for the synthesis of sulfinic esters. Results and Discussion: A novel electrochemical method for the synthesis of sulfinic esters from thiophenols and alcohols has been developed. Up to 27 examples of sulfinic esters have been synthesized using the current methods. This protocol shows good functional group tolerance as well as high efficiency. In addition, this protocol can be easily scaled up with good efficiency. Notably, heterocycle-containing substrates, including pyridine, thiophene, and benzothiazole, gave the desired products in good yields. A plausible reaction mechanism is proposed. Conclusion: This research not only provides a green and efficient method for the synthesis of sulfinic esters but also shows new applications of electrochemistry in organic synthesis. It is considered that this green and efficient synthetic protocol used to prepare sulfinic esters will have good applications in the future.

New Applications of Ph3PN—Li in Organic Synthesis and Heteroatom Chemistry

ChemInform ◽  
2003 ◽  
Vol 34 (7) ◽  
Author(s):  
Marc Taillefer ◽  
Nicolas Rahier ◽  
Ewelina Minta ◽  
Henri-Jean Cristau
Keyword(s):  
Organic Synthesis ◽  
New Applications

Silicon tetrachloride in organic synthesis: new applications for the vinylogous aldol reaction

Tetrahedron ◽  
2005 ◽  
Vol 61 (16) ◽  
pp. 4091-4097 ◽  
Author(s):  
Maria R. Acocella ◽  
Margherita De Rosa ◽  
Antonio Massa ◽  
Laura Palombi ◽  
Rosaria Villano ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Aldol Reaction ◽  
Silicon Tetrachloride ◽  
New Applications
Sign in / Sign up

Export Citation Format

Share Document