ChemInform Abstract: Synthesis, X-Ray Crystal Structure, and Reactivity of the Binuclear Copper(I) Complex ((Cu(3,5Me2-pz)(CNR))2) (R: cyclohexyl, 3,5Me2-pz: 3,5-dimethylpyrazolate) Toward RNCO (R: cyclohexyl), PhNCS, COS, and CS2. N,S Coordination of the

ChemInform ◽  
1990 ◽  
Vol 21 (40) ◽  
Author(s):  
G. A. ARDIZZOIA ◽  
M. A. ANGARONI ◽  
G. LA MONICA ◽  
N. MASCIOCCHI ◽  
M. MORET
1998 ◽  
Vol 53 (8) ◽  
pp. 871-874 ◽  
Author(s):  
G. Facchin ◽  
M. H. Torre ◽  
E. Kremer ◽  
O. E. Piro ◽  
E. J. Baran

Abstract The crystal structure of the binuclear Cu(II) complex [Cu(mef)2DMSO]2 (mef = deprotonated N-2,3-dimethylphenyl-anthranilic acid; DMSO = dimethylsulfoxide) has been determined by single-crystal X-ray diffractometry. It crystallizes in the triclinic space group P1̄ with Z = 1. IR and electronic spectra of the compound are also discussed briefly.


Polyhedron ◽  
1997 ◽  
Vol 16 (23) ◽  
pp. 4033-4038 ◽  
Author(s):  
Yang Ruina ◽  
Lin Kunhua ◽  
Hou Yimin ◽  
Wang Dongmei ◽  
Jin Douman

1989 ◽  
Vol 44 (3) ◽  
pp. 307-311 ◽  
Author(s):  
Yuzo Nishida ◽  
Miyuki Masumoto ◽  
Yutaka Mori

The crystal structure of the binuclear copper(II) complex. [Cu2(L)(2-pyridonato)] was determined by X-ray diffraction, where H3(L) represents the Schiff base ligand derived from 1,3-diaminopropane-2-ol and acetylacetone. Two copper(II) ions are bridged by alkoxide and 2-pyridonate groups with a Cu-Cu separation of 3.249(2) Å . Ferromagnetic interaction is found to be operating in this complex, which is attributed to the small dihedral angle (121°) between the two planes containing the copper(II) ion.


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