ChemInform Abstract: IR Matrix Isolation Studies of Hydrogen Bonds Involving C-H Bonds: Alkenes with Selected Bases

ChemInform ◽  
1990 ◽  
Vol 21 (39) ◽  
Author(s):  
M.-L. H. JENG ◽  
B. S. AULT
Keyword(s):  
Hydrogen Bonds ◽  
Matrix Isolation

The Infrared Matrix Isolation Spectra of Water Species in a Deuterium Matrix

1979 ◽  
Vol 32 (6) ◽  
pp. 1167 ◽  
Author(s):  
EJ Murby ◽  
ADE Pullin
Keyword(s):  
Hydrogen Bonds ◽  
Matrix Isolation ◽  
Water Dimer ◽  
Cyclic Structure ◽  
Water Species

The spectra of matrices of deuterium at c.7 K containing water species derived from D2O, H2O and mixtures of D2O and H2O have been obtained in the region 4000-1000 cm-1. Six bands have been assigned to the fundamentals of (H2O)2, of (D2O)2 and of deuterium-bonded HDO dimeric species.A preference for HDO to form HO-D. . .O (deuterium) bonds rather than DO-H. . .O (hydrogen)bonds has been observed. The spectra in matrices of deuterium are closely similar to those observed in nitrogen matrices and support an open, rather than a cyclic, structure for the water dimer.

scholarly journals Intermolecular Complexes and Molecular Conformations Directed by Hydrogen Bonds: Matrix Isolation and Ab Initio Studies

2019 ◽  
Vol 100 (1) ◽  
pp. 167-190
Author(s):  
Jyoti Saini ◽  
Pankaj Dubey ◽  
Kanupriya Verma ◽  
Ginny Karir ◽  
K. S. Viswanathan
Keyword(s):  
Hydrogen Bonds ◽  
Ab Initio ◽  
Matrix Isolation ◽  
Molecular Conformations ◽  
Intermolecular Complexes
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