ChemInform Abstract: A Simple and Short Synthesis of (Z)-13-Eicosen-10-one (V), the Sex Pheromone of the Peach Fruit Moth.

ChemInform ◽  
1990 ◽  
Vol 21 (36) ◽  
Author(s):  
S.-K. KANG ◽  
D.-H. LEE
2000 ◽  
Vol 3 (2) ◽  
pp. 83-88 ◽  
Author(s):  
Kyeung Sik Han ◽  
Jin Kyo Jung ◽  
Kyung Hee Choi ◽  
Sun Won Lee ◽  
Kyung Saeng Boo

2000 ◽  
Vol 65 (4) ◽  
pp. 524-538 ◽  
Author(s):  
Andreas Job ◽  
René Nagelsdiek ◽  
Dieter Enders

Serricornin is a female-produced sex pheromone of the cigarette beetle (Lasioderma serricorne), which is a pest of dried foodstuffs and tobacco. We report a versatile and short synthesis of all possible 6,7-syn-isomers of serricornin, including the natural isomer. Starting from the SAMP and RAMP derivatives of diethyl ketone we obtained four different enantiopure and diastereomerically pure serricornins. The main advantage of this method is that only a single kind of chiral starting material is needed for the construction of three stereogenic centers. During the synthesis further useful intermediates including (R)- and (S)-1-benzyloxy-2-methylpentan-3-one (4) and (2S,3R)- and (2R,3S)-1-iodo-3-(methoxy- methoxy)-2-methylpentane (9) were obtained.


1981 ◽  
Vol 45 (2) ◽  
pp. 439-442 ◽  
Author(s):  
Yoshinobu Naoshima ◽  
Mitsugu Kawakubo ◽  
Shoji Wakabayashi ◽  
Shûichi Hayashi
Keyword(s):  

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