ChemInform Abstract: Structure Sensitivity of Methane Oxidation Over Platinum and Palladium.

ChemInform ◽  
1990 ◽  
Vol 21 (28) ◽  
Author(s):  
R. F. HICKS ◽  
H. QI ◽  
M. L. YOUNG ◽  
R. G. LEE
Keyword(s):  
Methane Oxidation ◽  
Structure Sensitivity ◽  
Abstract Structure

ChemInform Abstract: Structure Sensitivity of the Marcus λ for Hydride Transfer Between NAD+ Analogues.

ChemInform ◽  
1988 ◽  
Vol 19 (18) ◽  
Author(s):  
M. M. KREEVOY ◽  
D. OSTOVIC ◽  
I.-S. H. LEE ◽  
D. A. BINDER ◽  
G. W. KING
Keyword(s):  
Hydride Transfer ◽  
Structure Sensitivity ◽  
Abstract Structure

Abstract: Structure sensitivity, steric hindrance, and surface chemistry

1974 ◽  
Vol 11 (1) ◽  
pp. 249-249
Author(s):  
Robert L. Burwell ◽  
Harold H. Kung ◽  
Donald Barry
Keyword(s):  
Surface Chemistry ◽  
Steric Hindrance ◽  
Structure Sensitivity ◽  
Abstract Structure

Structure sensitivity of methane oxidation on Pt/SiO2 of widely varying dispersity

1988 ◽  
Vol 37 (1) ◽  
pp. 89-93 ◽  
Author(s):  
M. Kobayashi ◽  
T. Kanno ◽  
A. Konishi ◽  
H. Takeda
Keyword(s):  
Methane Oxidation ◽  
Structure Sensitivity

Methane Oxidation on a Coverage Layer Study

2008 ◽  
Author(s):  
Juliana L. Rose ◽  
Pedro Paulo F. Gouvêa ◽  
Cláudio F. Mahler
Keyword(s):  
Methane Oxidation

Ultra-Low Amounts of Palladium (0.005-0.05 Wt% Pd) Supported on Titania: Remarkable Low-Temperature Activity for NO Reduction with CO and Structure-Function Property Relationships in Methane Oxidation

2020 ◽  
Author(s):  
Konstantin Khivantsev ◽  
Libor Kovarik ◽  
Nicholas R. Jaegers ◽  
János Szanyi ◽  
Yong Wang
Keyword(s):  
Nitric Oxide ◽  
Carbon Monoxide ◽  
Methane Oxidation ◽  
Steam Reforming ◽  
Methane Steam Reforming ◽  
Oxide Reduction ◽  
Water Steam ◽  
Methane Steam ◽  
Anatase Titania ◽  
Nitric Oxide Reduction

<p>Atomically dispersed Pd +2 cations with ultra-dilute loading of palladium (0.005-0.05 wt%) were anchored on anatase titania and characterized with FTIR, microscopy and catalytic tests. CO infrared adsorption produces a sharp, narrow mono-carbonyl Pd(II)-CO band at ~2,130 cm<sup>-1</sup> indicating formation of highly uniform and stable Pd+2 ions on anatase titania. The 0.05 wt% Pd/TiO<sub>2</sub> sample was evaluated for methane combustion under dry and wet (industrially relevant) conditions in the presence and absence of carbon monoxide. Notably, we find the isolated palladium atoms respond dynamically upon oxygen concentration modulation (switching-on and switching off). When oxygen is removed from the wet methane stream, palladium ions are reduced to metallic state by methane and catalyze methane steam reforming instead of complete methane oxidation. Re-admission of oxygen restores Pd<sup>+2</sup> cations and switches off methane steam reforming activity. Moreover, 0.05 wt% Pd/TiO<sub>2</sub> is a competent CO oxidation catalyst in the presence of water steam with 90% CO conversion and TOF ~ 4,000 hr<sup>-1</sup> at 260 ⁰C. </p><p>More importantly, we find that diluting 0.05 wt% Pd/titania sample with titania to ultra-low 0.005 wt% palladium loading produces a remarkably active material for nitric oxide reduction with carbon monoxide under industrially relevant conditions with >90% conversion of nitric oxide at 180 ⁰C (~460 ppm NO and 150 L/g*hr flow rate in the presence of >2% water steam) and TOF ~6,000 hr<sup>-1</sup>. Pd thus outperforms state-of-the-art rhodium containing catalysts with (15-20 times higher rhodium loading; rhodium is ~ 3 times more expensive than palladium). Furthermore, palladium catalysts are more selective towards nitrogen and produce significantly less ammonia relative to the more traditional rhodium catalysts due to lower Pd amount nd lower water-gas-shift activity. Our study is the first example of utilizing ultra-low (0.05 wt% and less) noble metal (Pd) amounts to produce heterogeneous catalysts with extraordinary activity for nitric oxide reduction. This opens up a pathway to study other Pd, Pt and Rh containing materials with ultra-low loadings of expensive noble metals dispersed on titania or titania-coated oxides for industrially relevant nitric oxide abatement.</p>

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