ChemInform Abstract: Skeletal Rearrangements of Deprotonated Organosilanes in the Gas Phase. Silicon-Oxygen Bond Formation.

ChemInform ◽  
1990 ◽  
Vol 21 (27) ◽  
Author(s):  
K. M. DOWNARD ◽  
J. H. BOWIE ◽  
R. N. HAYES
1990 ◽  
Vol 43 (3) ◽  
pp. 511 ◽  
Author(s):  
KM Downard ◽  
JH Bowie ◽  
RN Hayes

Trimethylsilyl anions containing additional alkoxy, ketone or carboxylic acid funtionality undergo a variety of rearrangement reactions upon collisional activation. The most common are those which involve production of Si -O bonds, either by formation of Me3SiO- or by elimination of Me3SiOH.


2010 ◽  
Vol 39 (39) ◽  
pp. 9361 ◽  
Author(s):  
Vincenzo Abbate ◽  
Alan R. Bassindale ◽  
Kurt F. Brandstadt ◽  
Rachel Lawson ◽  
Peter G. Taylor

2005 ◽  
Vol 8 (12) ◽  
pp. 1082-1084 ◽  
Author(s):  
Kaustavmoni Deka ◽  
Rupam Jyoti Sarma ◽  
Jubaraj B. Baruah

2011 ◽  
Vol 105 (2) ◽  
pp. 268-275 ◽  
Author(s):  
Vincenzo Abbate ◽  
Alan R. Bassindale ◽  
Kurt F. Brandstadt ◽  
Peter G. Taylor

Author(s):  
Ayesha Jalil ◽  
Yaxin O Yang ◽  
Zhendong Chen ◽  
Rongxuan Jia ◽  
Tianhao Bi ◽  
...  

: Hypervalent iodine reagents are a class of non-metallic oxidants have been widely used in the construction of several sorts of bond formations. This surging interest in hypervalent iodine reagents is essentially due to their very useful oxidizing properties, combined with their benign environmental character and commercial availability from the past few decades ago. Furthermore, these hypervalent iodine reagents have been used in the construction of many significant building blocks and privileged scaffolds of bioactive natural products. The purpose of writing this review article is to explore all the transformations in which carbon-oxygen bond formation occurred by using hypervalent iodine reagents under metal-free conditions


ChemInform ◽  
2008 ◽  
Vol 39 (1) ◽  
Author(s):  
Laetitia Coudray ◽  
Isabelle Abrunhosa-Thomas ◽  
Jean-Luc Montchamp

1970 ◽  
Vol 3 (2) ◽  
pp. 241-242 ◽  
Author(s):  
T. H. Kinstle ◽  
W. R. Oliver ◽  
L. A. Ochrymowycz

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