ChemInform Abstract: Michael Addition of Methyl 2-(Trimethylsilyl)propenoate with Organomagnesiums or Organolithiums Leading to 1:1 and/or 2:1 Adducts and Subsequent Peterson Olefination by Condensation with Carbonyl Compounds.

J. TANAKA; S. KANEMASA; Y. NINOMIYA; O. TSUGE

doi:10.1002/chin.199025101

ChemInform Abstract: Michael Addition of Methyl 2-(Trimethylsilyl)propenoate with Organomagnesiums or Organolithiums Leading to 1:1 and/or 2:1 Adducts and Subsequent Peterson Olefination by Condensation with Carbonyl Compounds.

ChemInform ◽

10.1002/chin.199025101 ◽

1990 ◽

Vol 21 (25) ◽

Author(s):

J. TANAKA ◽

S. KANEMASA ◽

Y. NINOMIYA ◽

O. TSUGE

Keyword(s):

Michael Addition ◽

Carbonyl Compounds ◽

Peterson Olefination

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Michael Addition of Methyl 2-(Trimethylsilyl)propenoate with Organomagnesiums or Organolithiums Leading to 1:1 and/or 2:1 Adducts and Subsequent Peterson Olefination by Condensation with Carbonyl Compounds

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.63.466 ◽

1990 ◽

Vol 63 (2) ◽

pp. 466-475 ◽

Cited By ~ 22

Author(s):

Junji Tanaka ◽

Shuji Kanemasa ◽

Yusuke Ninomiya ◽

Otohiko Tsuge

Keyword(s):

Michael Addition ◽

Carbonyl Compounds ◽

Peterson Olefination

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Copper(II) Tetrafluoroborate as a Novel and Highly Efficient Catalyst for Michael Addition of Mercaptans to α,β-Unsaturated Carbonyl Compounds.

ChemInform ◽

10.1002/chin.200526036 ◽

2005 ◽

Vol 36 (26) ◽

Author(s):

Sanjeev K. Garg ◽

Raj Kumar ◽

Asit K. Chakraborti

Keyword(s):

Michael Addition ◽

Carbonyl Compounds ◽

Efficient Catalyst ◽

Highly Efficient

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Michael addition of carbonyl compounds to nitroolefins under the catalysis of new pyrrolidine-based bifunctional organocatalysts

Organic & Biomolecular Chemistry ◽

10.1039/c7ob02798b ◽

2018 ◽

Vol 16 (6) ◽

pp. 924-935 ◽

Cited By ~ 7

Author(s):

A. Castán ◽

R. Badorrey ◽

J. A. Gálvez ◽

P. López-Ram-de-Víu ◽

M. D. Díaz-de-Villegas

Keyword(s):

Michael Addition ◽

Carbonyl Compounds ◽

Asymmetric Michael Addition ◽

Aldehydes And Ketones

Novel bifunctional pyrrolidine-based organocatalysts applicable for the asymmetric Michael addition of aldehydes and ketones to nitroolefins have been developed.

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Nucleofugal behavior of a β-shielded α-cyanovinyl carbanion

Beilstein Journal of Organic Chemistry ◽

10.3762/bjoc.14.281 ◽

2018 ◽

Vol 14 ◽

pp. 3018-3024

Author(s):

Rudolf Knorr ◽

Barbara Schmidt

Keyword(s):

Michael Addition ◽

Carbonyl Compounds ◽

Room Temperature ◽

Experimental Conditions ◽

Metal Free ◽

Metal Derivatives ◽

Carbonyl Addition ◽

Derivatives Of

Sterically well-shielded against unsolicited Michael addition and polymerization reactions, α-metalated α-(1,1,3,3-tetramethylindan-2-ylidene)acetonitriles added reversibly to three small aldehydes and two bulky ketones at room temperature. Experimental conditions were determined for transfer of the nucleofugal title carbanion unit between different carbonyl compounds. These readily occurring retro-additions via C–C(O) bond fission may also be used to generate different metal derivatives of the nucleofugal anions as equilibrium components. Fluoride-catalyzed, metal-free desilylation admitted carbonyl addition but blocked the retro-addition.

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A Natural Phosphate and Doped-Catalyzed Michael Addition of Mercaptans to α,β-Unsaturated Carbonyl Compounds.

ChemInform ◽

10.1002/chin.200313093 ◽

2003 ◽

Vol 34 (13) ◽

Author(s):

Younes Abrouki ◽

Mohamed Zahouily ◽

Ahmed Rayadh ◽

Bouchaib Bahlaouan ◽

Said Sebti

Keyword(s):

Michael Addition ◽

Carbonyl Compounds ◽

Natural Phosphate

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ChemInform Abstract: Eco-Friendly Polyethylene Glycol Promoted Michael Addition Reactions of α,β-Unsaturated Carbonyl Compounds.

ChemInform ◽

10.1002/chin.200911035 ◽

2009 ◽

Vol 40 (11) ◽

Author(s):

Dalip Kumar ◽

Gautam Patel ◽

Braja G. Mishra ◽

Rajender S. Varma

Keyword(s):

Polyethylene Glycol ◽

Michael Addition ◽

Carbonyl Compounds ◽

Addition Reactions

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Asymmetric Michael addition of 2-alkoxyphenyl α-substituted nitroacetates to non-prochiral α,β-unsaturated carbonyl compounds catalyzed by podand-type alkali metal 2′-substituted 1,1′-binaphthalen-2-oxides

Tetrahedron Letters ◽

10.1016/j.tetlet.2014.07.046 ◽

2014 ◽

Vol 55 (35) ◽

pp. 4923-4926 ◽

Cited By ~ 6

Author(s):

Toyohiro Otani ◽

Akifumi Sugawara ◽

Yasufumi Tamai

Keyword(s):

Alkali Metal ◽

Michael Addition ◽

Carbonyl Compounds ◽

Asymmetric Michael Addition

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ChemInform Abstract: A Convenient Methodology for Nitro-Michael Addition of Carbonyl Compounds Catalyzed by L-Proline Using Microwave Heating.

ChemInform ◽

10.1002/chin.201032035 ◽

2010 ◽

Vol 41 (32) ◽

pp. no-no

Author(s):

Alessio Russo ◽

Nicholas E. Leadbeater ◽

Alessandra Lattanzi

Keyword(s):

Microwave Heating ◽

Michael Addition ◽

Carbonyl Compounds

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ChemInform Abstract: Fluoroboric Acid Adsorbed on Silica-Gel (HBF4-SiO2) as a New, Highly Efficient and Reusable Heterogeneous Catalyst for thia-Michael Addition to α,β-Unsaturated Carbonyl Compounds.

ChemInform ◽

10.1002/chin.200841037 ◽

2008 ◽

Vol 39 (41) ◽

Author(s):

Gaurav Sharma ◽

Raj Kumar ◽

Asit K. Chakraborti

Keyword(s):

Heterogeneous Catalyst ◽

Silica Gel ◽

Michael Addition ◽

Carbonyl Compounds ◽

Highly Efficient

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Michael Addition of Selenoamides to α,β-Unsaturated Carbonyl Compounds: Stereocontrolled Synthesis of δ-Oxo Selenoamides and Their Reactivity

Organic Letters ◽

10.1021/ol990365s ◽

2000 ◽

Vol 2 (3) ◽

pp. 311-313 ◽

Cited By ~ 16

Author(s):

Toshiaki Murai ◽

Akiko Suzuki ◽

Tatsuya Ezaka ◽

Shinzi Kato

Keyword(s):

Michael Addition ◽

Carbonyl Compounds ◽

Stereocontrolled Synthesis

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