ChemInform Abstract: Synthesis of 1,4-, 2,4-, and 3,4-Dimethylphenanthrenes: A Novel Deoxygenation of Arene 1,4-Endoxides with Trimethylsilyl Iodide.

ChemInform ◽  
1990 ◽  
Vol 21 (19) ◽  
Author(s):  
K. JUNG ◽  
M. KOREEDA
Keyword(s):  
Trimethylsilyl Iodide

The use of trimethylsilyl iodide as a synthon in coordination chemistry

2002 ◽  
Vol 330 (1) ◽  
pp. 197-212 ◽  
Author(s):  
G.Jeffery Leigh ◽  
J.Roger Sanders ◽  
Peter B. Hitchcock ◽  
Jaisa Soares Fernandes ◽  
Maria Togrou
Keyword(s):  
Coordination Chemistry ◽  
Trimethylsilyl Iodide

Nitrones and Oxaziridines. XXXVI. Synthesis of Cyclic Thiohydroxamic Acids

1988 ◽  
Vol 41 (1) ◽  
pp. 37 ◽  
Author(s):  
DS Black ◽  
KL Ooi
Keyword(s):  
Hydroxamic Acids ◽  
Demethylating Agent ◽  
Ethyl Xanthate ◽  
Cyclic Hydroxamic Acids ◽  
Trimethylsilyl Iodide ◽  
Potassium Ethyl Xanthate

2-Cyano-1-pyrroline 1-oxides (1) could not be converted directly into the related cyclic thiohydroxamic acids (8). Potassium ethyl xanthate transformed nitrones (1) into the imidates (2). The cyclic hydroxamic acids (4) can be converted into the thiohydroxamic acids (8) via the methoxypyrrolidinones (5) and the methoxypyrrolidine thiones (6), making use of sodium p- tolylmercaptide as the demethylating agent. Reaction of methoxy thiones (6) with trimethylsilyl iodide led to the formation of the 2-methylthio-1-pyrroline 1-oxides (7).

Mild methods for the generation of trimethylsilyl iodide

1978 ◽  
Vol 19 (39) ◽  
pp. 3657-3660 ◽  
Author(s):  
Michael E. Jung ◽  
Todd A. Blumenkopf
Keyword(s):  
Trimethylsilyl Iodide

Trimethylsilyl Iodide-Promoted Aza-Prins Cyclization for the Synthesis of 4-Iodopiperidines

2010 ◽  
Vol 93 (10) ◽  
pp. 2023-2025 ◽  
Author(s):  
Gowravaram Sabitha ◽  
Sukant Kishore Das ◽  
Rangavajjula Srinivas ◽  
Jhillu S. Yadav
Keyword(s):  
Prins Cyclization ◽  
Trimethylsilyl Iodide

Trimethylsilyl iodide as a halide exchange reagent in inorganic chemistry: synthesis and structure of Cp2*ThI2 (Cp* = η5-C5Me5)

1998 ◽  
Vol 274 (2) ◽  
pp. 232-235 ◽  
Author(s):  
Daniel Rabinovich ◽  
Simon G. Bott ◽  
Jon B. Nielsen ◽  
Kent D. Abney
Keyword(s):  
Inorganic Chemistry ◽  
Trimethylsilyl Iodide ◽  
Halide Exchange
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