ChemInform Abstract: Synthesis of Cerebroside B1b with Antiulcerogenic Activity. Part 2. Total Synthesis and Determination of Absolute Configuration of Cerebroside B1b and Its Stereoisomers.

ChemInform ◽  
1990 ◽  
Vol 21 (15) ◽  
Author(s):  
S. KODATO ◽  
M. NAKAGAWA ◽  
T. HINO
Keyword(s):  
Total Synthesis ◽  
Absolute Configuration ◽  
Determination Of Absolute Configuration ◽  
Antiulcerogenic Activity

(-)-Strempeliopine, stereoselective total synthesis and the determination of absolute configuration

1986 ◽  
Vol 51 (8) ◽  
pp. 1731-1742 ◽  
Author(s):  
Josef Hájíček ◽  
Jan Trojánek
Keyword(s):  
Circular Dichroism ◽  
Total Synthesis ◽  
Absolute Configuration ◽  
Determination Of Absolute Configuration ◽  
Natural Base ◽  
The Absolute ◽  
Circular Dichroïsm

A synthesis of (±)-strempeliopine (II) is described, the key step of which is the stereoselective reductive rearrangement of 18-methylene-1,2-dehydroaspidospermidine (XI). The absolute configuration of the natural (-)-base II was determined as (2S, 7R, 20R, 21R) on the basis of its synthesis from (+)-18-methylenevincadifformine (XVII) the configuration of which was derived from a comparison of circular dichroism properties of bases with a β-anilinoacrylate chromophore. The biogenesis of the alkaloids of the schizozygane type is discussed.

Determination of absolute configuration of trimeric indole alkaloid, psychotrimine, by first asymmetric total synthesis

2010 ◽  
Vol 46 (14) ◽  
pp. 2501 ◽  
Author(s):  
Nobuaki Takahashi ◽  
Takeshi Ito ◽  
Yohei Matsuda ◽  
Noriyuki Kogure ◽  
Mariko Kitajima ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Absolute Configuration ◽  
Indole Alkaloid ◽  
Asymmetric Total Synthesis ◽  
Determination Of Absolute Configuration

ChemInform Abstract: Determination of Absolute Configuration of Trimeric Indole Alkaloid, Psychotrimine, by First Asymmetric Total Synthesis.

ChemInform ◽  
2010 ◽  
Vol 41 (32) ◽  
pp. no-no
Author(s):  
Nobuaki Takahashi ◽  
Takeshi Ito ◽  
Yohei Matsuda ◽  
Noriyuki Kogure ◽  
Mariko Kitajima ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Absolute Configuration ◽  
Indole Alkaloid ◽  
Asymmetric Total Synthesis ◽  
Determination Of Absolute Configuration

Total synthesis and determination of absolute configuration of cerebroside B1b and its stereoisomers

1987 ◽  
Vol 28 (50) ◽  
pp. 6281-6284 ◽  
Author(s):  
Masako Nakagawa ◽  
Shin-ichi Kodato ◽  
Kiyoshi Nakayama ◽  
Tohru Hino
Keyword(s):  
Total Synthesis ◽  
Absolute Configuration ◽  
Determination Of Absolute Configuration

First Stereoselective Total Synthesis of Sporostatin and Determination of Absolute Configuration

Synlett ◽  
2009 ◽  
Vol 2009 (05) ◽  
pp. 790-792 ◽  
Author(s):  
J. Yadav ◽  
N. Thrimurtulu ◽  
K. Gayathri ◽  
B. Reddy ◽  
A. Prasad
Keyword(s):  
Total Synthesis ◽  
Absolute Configuration ◽  
Determination Of Absolute Configuration
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