ChemInform Abstract: Highly Stereoselective Reduction of Methyl Ketone Complexes of the Chiral Lewis Acid ((η5-C5H5)Re(NO)(PPh3))+ by K((s-C4H9)3BH). Synthesis of Optically Active Secondary Alcohols and Derivatives.

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A chiral Lewis acid-promoted cyclopropanation using a phenyliodonium ylide as the carbene precursor was developed. An EPR spectroscopy study supported a stepwise biradical mechanism.


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