ChemInform Abstract: Pentamethylcyclopentadienylrhodaborane Chemistry. Part 3. The Reaction of ((Rh(η5-C5Me5)Cl2)2) with closo-(B10H10)2- and arachno-B10H12-6,9-(PMe2Ph)2, and the Characterization of Some Novel Rhodaboranes by X-Ray Diffraction Analysis a

ChemInform ◽  
1988 ◽  
Vol 19 (4) ◽  
Author(s):  
X. L. R. FONTAINE ◽  
H. FOWKES ◽  
N. N. GREENWOOD ◽  
J. D. KENNEDY ◽  
M. THORNTON-PETT
Keyword(s):  
Diffraction Analysis ◽  
X Ray Diffraction ◽  
X Ray

Synthesis and Characterization of Tetrakis(pentafluoroethyl)germane

Synthesis ◽  
2017 ◽  
Vol 49 (11) ◽  
pp. 2389-2393 ◽  
Author(s):  
Stefanie Pelzer ◽  
Beate Neumann ◽  
Hans-Georg Stammler ◽  
Nikolai Ignat’ev ◽  
Reint Eujen ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Nmr Spectroscopy ◽  
Ir Spectroscopy ◽  
Diffraction Analysis ◽  
Spectroscopic Characterization ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Comprehensive Characterization

This paper describes the synthesis and comprehensive characterization of tetrakis(pentafluoroethyl)germane. In addition to a complete NMR spectroscopic characterization, including the rarely used 73Ge NMR spectroscopy, Ge(C2F5)4 was studied by IR spectroscopy, mass spectrometry as well as X-ray diffraction analysis. A 73Ge NMR investigation as well as an X-ray diffraction study of the related germane Ge(CF3)4 are also included.

Synthesis and characterization of the pentazolate anion cyclo-N5ˉ in (N5)6(H3O)3(NH4)4Cl

Science ◽  
2017 ◽  
Vol 355 (6323) ◽  
pp. 374-376 ◽  
Author(s):  
Chong Zhang ◽  
Chengguo Sun ◽  
Bingcheng Hu ◽  
Chuanming Yu ◽  
Ming Lu
Keyword(s):  
Thermal Analysis ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Decomposition Temperature ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Onset Decomposition Temperature ◽  
The Stability

Pentazole (HN5), an unstable molecular ring comprising five nitrogen atoms, has been of great interest to researchers for the better part of a century. We report the synthesis and characterization of the pentazolate anion stabilized in a (N5)6(H3O)3(NH4)4Cl salt. The anion was generated by direct cleavage of the C–N bond in a multisubstituted arylpentazole using m-chloroperbenzoic acid and ferrous bisglycinate. The structure was confirmed by single-crystal x-ray diffraction analysis, which highlighted stabilization of the cyclo-N5ˉ ring by chloride, ammonium, and hydronium. Thermal analysis indicated the stability of the salt below 117°C on the basis of thermogravimetry-measured onset decomposition temperature.

SYNTHESIS AND CHARACTERIZATION OF La2Ca3Cu4Oy

1999 ◽  
Vol 13 (12n13) ◽  
pp. 451-453
Author(s):  
K. JEYABALAN ◽  
L. K. KALIYAPERUMAL
Keyword(s):  
Diffraction Analysis ◽  
Lattice Parameters ◽  
Synthesis And Characterization ◽  
Orthorhombic Structure ◽  
X Ray Diffraction ◽  
X Ray

Synthesis and characterization of La 2 Ca 3 Cu 4 O y compound is reported here. The powder X-ray diffraction analysis shows that the system belongs to an orthorhombic structure and the lattice parameters are a = 3.814(4)Å, b = 3.930(5)Å and c = 34.772(3)Å.

Characterization of Mycelium-Like Material Formed During Drying of Salt Stock Prunes

1994 ◽  
Vol 57 (9) ◽  
pp. 817-819
Author(s):  
ROBIN Y.-Y. CHIOU ◽  
WEN-CHING TZENG ◽  
KUO-FONG HUANG
Keyword(s):  
Organic Matter ◽  
Sodium Chloride ◽  
Citric Acid ◽  
Diffraction Analysis ◽  
Diffraction Pattern ◽  
X Ray Diffraction ◽  
X Ray

Material with the appearance of mold mycelium was formed on salt stock prunes during drying. The moisture-free mycelium-like material consisted of 98.5 to 98.7% sodium chloride (NaCl), 1.67% organic matter and 0.165% acidity expressed as citric acid. X-ray diffraction analysis of the material revealed a diffraction pattern similar to that of NaCl. Formation of the material was dependent upon the efficiency and extent of drying. However, the material was not observed on deskinned salt stock prunes subjected to drying.

Sign in / Sign up

Export Citation Format

Share Document