ChemInform Abstract: COMPLEXES CONTAINING CARBON SULFIDES AND -SELENIDES AS LIGANDS. PART 16. FRAGMENTATION AND RECOMBINATION OF CARBON DISULFIDE AND CARBON SULFIDE SELENIDE (CSSE) IN THE COORDINATION SPHERES OF PLATINUM METALS

1985 ◽  
Vol 16 (44) ◽  
Author(s):  
M. EBNER ◽  
H. OTTO ◽  
H. WERNER
Keyword(s):  
Carbon Disulfide ◽  
Platinum Metals ◽  
Carbon Sulfide ◽  
Coordination Spheres ◽  
Carbon Sulfides

Carbon sulfide(1+) (A2.PI.i-X2.SIGMA.+) chemiluminescence produced in the reaction of carbon(1+) (2P) with carbon disulfide at thermal energy

1988 ◽  
Vol 92 (5) ◽  
pp. 1163-1164 ◽  
Author(s):  
Masaharu Tsuji ◽  
Kazumi Mizukami ◽  
Hiroshi Obase ◽  
Yukio Nishimura
Keyword(s):  
Carbon Disulfide ◽  
Thermal Energy ◽  
Carbon Sulfide

On the detection of higher order carbon sulfides (CSx; x=4–6) in low temperature carbon disulfide ices

2013 ◽  
Vol 577 ◽  
pp. 42-47 ◽  
Author(s):  
Surajit Maity ◽  
Y.S. Kim ◽  
Ralf I. Kaiser ◽  
Hong Mao Lin ◽  
Bian Jian Sun ◽  
...  
Keyword(s):  
Low Temperature ◽  
Carbon Disulfide ◽  
Higher Order ◽  
Carbon Sulfides

Improvement in the Fock test for determining the reactivity of dissolving pulp

TAPPI Journal ◽  
2013 ◽  
Vol 12 (11) ◽  
pp. 21-26 ◽  
Author(s):  
CHAO TIAN ◽  
LINQIANG ZHENG ◽  
QINGXIAN MIAO ◽  
CHRIS NASH ◽  
CHUNYU CAO ◽  
...  
Keyword(s):  
Moisture Content ◽  
Sodium Hydroxide ◽  
Constant Temperature ◽  
Carbon Disulfide ◽  
Testing Procedure ◽  
Dissolving Pulp ◽  
Water Bath ◽  
Testing Conditions ◽  
Pulp Sample ◽  
Fock Reactivity

The Fock test is widely used for assessing the reactivity of dissolving pulp. The objective of this study was to modify the method to improve the repeatability of the test. Various parameters that affect the repeatability of the Fock test were investigated. The results showed that Fock reactivity is dependent on testing conditions affecting the xanthation between cellulose and carbon disulfide, such as the moisture content of the pulp sample, sodium hydroxide (NaOH) concentration, xanthation temperature, carbon disulfide dosage, and xanthation time. The repeatability of the test was significantly improved using the following modified testing procedure: air dried sample in the constant temperature/humidity room, xanthation temperature of 66°F (19°C) in a water bath, xanthation time of 3 h, NaOH concentration of 9% (w/w), and 1.3 mL carbon disulfide.

Xenon Trioxide Adducts of O-Donor Ligands; [(CH3)2CO]3XeO3, [(CH3)2SO]3(XeO3)2, (C5H5NO)3(XeO3)2, and [(C6H5)3PO]2XeO3

2018 ◽  
Author(s):  
Katherine Marczenko ◽  
James Goettel ◽  
Gary Schrobilgen
Keyword(s):  
Room Temperature ◽  
Triphenylphosphine Oxide ◽  
Donor Ligands ◽  
Mechanical Shock ◽  
X Ray Diffraction ◽  
X Ray ◽  
Oxygen Coordination ◽  
Xenon Trioxide ◽  
Distorted Octahedra ◽  
Coordination Spheres

Oxygen coordination to the Xe(VI) atom of XeO<sub>3</sub> was observed in its adducts with triphenylphosphine oxide, dimethylsulfoxide, pyridine-N-oxide, and acetone. The crystalline adducts were characterized by low-temperature, single-crystal X-ray diffraction and Raman spectroscopy. Unlike solid XeO<sub>3</sub>, which detonates when mechanically or thermally shocked, the solid [(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>PO]<sub>2</sub>XeO<sub>3</sub>, [(CH<sub>3</sub>)<sub>2</sub>SO]<sub>3</sub>(XeO<sub>3</sub>)<sub>2</sub>,<sub> </sub>and (C<sub>5</sub>H<sub>5</sub>NO)<sub>3</sub>(XeO<sub>3</sub>)<sub>2</sub> adducts are insensitive to mechanical shock, but undergo rapid deflagration when ignited by a flame. Both [(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>PO]<sub>2</sub>XeO<sub>3 </sub>and (C<sub>5</sub>H<sub>5</sub>NO)<sub>3</sub>(XeO<sub>3</sub>)<sub>2</sub> are air-stable whereas [(CH<sub>3</sub>)<sub>2</sub>SO]<sub>3</sub>(XeO<sub>3</sub>)<sub>2</sub> slowly decomposes over several days and [(CH<sub>3</sub>)<sub>2</sub>CO]<sub>3</sub>XeO<sub>3</sub> undergoes adduct dissociation at room temperature. The xenon coordination sphere of [(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>PO]<sub>2</sub>XeO<sub>3</sub> is a distorted square pyramid which provides the first example of a five-coordinate XeO<sub>3</sub> adduct. The xenon coordination spheres of the remaining adducts are distorted octahedra comprised of three Xe---O secondary contacts that are approximately trans to the primary Xe–O bonds of XeO<sub>3</sub>. Quantum-chemical calculations were used to assess the Xe---O adduct bonds, which are predominantly electrostatic σ-hole bonds between the nucleophilic oxygen atoms of the bases and the σ-holes of the xenon atoms.

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