ChemInform Abstract: SODIUM IODIDE/BORON TRIFLUORIDE ETHERATE: A MILD REAGENT SYSTEM FOR THE CONVERSION OF ALLYLIC AND BENZYLIC ALCOHOLS INTO CORRESPONDING IODIDES AND SULFOXIDES INTO SULFIDES

1985 ◽  
Vol 16 (39) ◽  
Author(s):  
Y. D. VANKAR ◽  
C. T. RAO
Keyword(s):  
Boron Trifluoride ◽  
Sodium Iodide ◽  
Boron Trifluoride Etherate ◽  
Benzylic Alcohols

scholarly journals New System of Deprotection Step for the Hydroxide Radicals: Boron Trifluoride Etherate/Sodium Iodide

2011 ◽  
Vol 3 (3) ◽  
Author(s):  
Yuqing Cao ◽  
Xiaojun Yang ◽  
Dingxiang Du ◽  
Xiangtao Xu ◽  
Fangrui Song ◽  
...  
Keyword(s):  
Boron Trifluoride ◽  
Sodium Iodide ◽  
Boron Trifluoride Etherate ◽  
Hydroxide Radicals ◽  
New System

Organothallium compounds. XVIII. The effect of antimony pentafluoride and fluorosulfuric acid on the thallation of polyfluoroarenes

1982 ◽  
Vol 35 (8) ◽  
pp. 1587 ◽  
Author(s):  
GB Deacon ◽  
RNM Smith
Keyword(s):  
Boron Trifluoride ◽  
Sodium Iodide ◽  
Boron Trifluoride Etherate ◽  
Antimony Pentafluoride ◽  
Aqueous Sodium ◽  
Organothallium Compounds

The polyfluoroarenes m-H2C6F4, m-O2NC6F4H, m- and p-BrC6F4H, (p-HC6F4)2, C6F5H, 1,3,5-F3C6H3 and m-FSO2C6F4H have been thallated by thallic trifluoroacetate in fluorosulfuric acid in the presence of antimony pentafluoride. Substantial dithallation of m-H2F4 and 1,3,5-F3C6H3 and slight trithallation of the latter have been achieved. The products were identified by conversion into the corresponding polyfluoroiodoarenes on reaction with aqueous sodium iodide. From the reaction with pentafluorobenzene, pentafluorophenylthallium(III) species have been characterized. 1,2,4,5-Tetrafluoro-3-methoxybenzene was thallated by thallic trifluoroacetate in 1,2-dichloroethane in the presence of boron trifluoride etherate, but C6F5H and p-MeC6F4H failed to react.

Synthesis of o-isopentenylphenols

1971 ◽  
Vol 24 (11) ◽  
pp. 2355 ◽  
Author(s):  
J Hlubucek ◽  
E Ritchie ◽  
WC Taylor
Keyword(s):  
Phosphoric Acid ◽  
Zinc Chloride ◽  
Boron Trifluoride ◽  
Boron Trifluoride Etherate ◽  
Stannic Chloride ◽  
Counter Ion

The effect of the solvent and the counter-ion on the ring alkylation of 3- and 4-methoxyphenols by isopentenyl bromide has been examined. Under strictly anhydrous conditions good and consistent yields of the o- isopentenylphenols were obtained with the combination potassium- toluene, but sodium-toluene was more convenient. ��� Boron trifluoride etherate was more satisfactory than stannic chloride, zinc chloride, or phosphoric acid in catalysing the condensation of 3- and 4-methoxy-phenols with 2-methylbut-3-en-2-ol to the corresponding o-isopentenylphenols. Aryl α,α-dimethylpropargyl ethers were partially hydrogenated to the corresponding α,α- dimethylallyl ethers which rearranged in boiling N,N-diethyl-aniline to o-isopentenylphenols in high overall yield.

scholarly journals Synthesis of 5,6,7,8-Tetrahydroquinolines by Thermolysis of Oxime O-Allyl Ethers in the Presence of Boron Trifluoride Etherate.

1993 ◽  
Vol 41 (7) ◽  
pp. 1297-1298 ◽  
Author(s):  
Junko KOYAMA ◽  
Tamaki OGURA ◽  
Kiyoshi TAGAHARA ◽  
Masaaki MIYASHITA ◽  
Hiroshi IRIE
Keyword(s):  
Boron Trifluoride ◽  
Boron Trifluoride Etherate ◽  
Allyl Ethers
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