ChemInform Abstract: CHEMISTRY OF POLYFUNCTIONAL MOLECULES. 83. REACTIONS OF BIS(μ-N,N-BIS(DIPHENYLPHOSPHINO)METHYLAMINE-P,P′)-μ-CARBONYL-BIS(CHLORORH# ODIUM(I))(RH-RH) WITH ALKALI METAL HALIDES, PSEUDOHALIDES, AND SULFUR DIOXIDE

1985 ◽  
Vol 16 (36) ◽  
Author(s):  
J. ELLERMANN ◽  
G. SZUCSANYI
Keyword(s):  
Sulfur Dioxide ◽  
Alkali Metal ◽  
Metal Halides ◽  
Alkali Metal Halides

Molten potassium pyrosulfate: the reactions of 12 alkali-metal halides

1984 ◽  
Vol 37 (1) ◽  
pp. 191 ◽  
Author(s):  
PJ Mineely ◽  
SA Tariq
Keyword(s):  
Sulfur Dioxide ◽  
Alkali Metal ◽  
Reducing Power ◽  
Reduction Product ◽  
Metal Halides ◽  
Sodium Potassium ◽  
Reduction Reactions ◽  
Oxidation Reduction ◽  
Alkali Metal Halides

The oxidation-reduction reactions of 12 alkali-metal halides with molten potassium pyrosulfate were studied. Chlorides, bromides and iodides of sodium, potassium, rubidium and caesium were found to be oxidized to produce chlorine, bromine and iodine respectively. Sulfur dioxide was found to be the main reduction product. The reactions between chlorides and pyrosulfate were slow and incomplete, whereas reactions of bromides and iodides were fast and complete. The order of the oxidizability (reducing power) of the halides by pyrosulfate, the temperatures, and stoichiometries of the reactions have been determined.

scholarly journals Environmentally Benign Electrophilic Halogenation of Naphthalenes by H<sub>2</sub>O<sub>2</sub>—Alkali Metal Halides in An Aqueous Cationic Micellar Media

2012 ◽  
Vol 02 (03) ◽  
pp. 254-261 ◽  
Author(s):  
Kancharla Rajendar Reddy ◽  
Sariah Sana ◽  
Kusampally Uppalaiah ◽  
Kamatala Chinna Rajanna ◽  
Puppala Veerasomaiah
Keyword(s):  
Alkali Metal ◽  
Environmentally Benign ◽  
Micellar Media ◽  
Metal Halides ◽  
Alkali Metal Halides
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