ChemInform Abstract: REDOX AND MAGNETIC PROPERTIES OF BINUCLEAR COPPER COMPLEXES

1985 ◽  
Vol 16 (36) ◽  
Author(s):  
J. M. LATOUR ◽  
D. LIMOSIN ◽  
S. S. TANDON
Keyword(s):  
Magnetic Properties ◽  
Copper Complexes ◽  
Binuclear Copper

Redox and magnetic properties of binuclear copper complexes

1985 ◽  
Vol 107 (1) ◽  
pp. L1-L2 ◽  
Author(s):  
J.M. Latour ◽  
D. Limosin ◽  
S.S. Tandon
Keyword(s):  
Magnetic Properties ◽  
Copper Complexes ◽  
Binuclear Copper

Molecular structures and magnetic properties of .mu.-phenolato binuclear copper(II) complexes incorporating chloro, hydroxo, and azido exogenous bridging ligands

1988 ◽  
Vol 27 (21) ◽  
pp. 3710-3716 ◽  
Author(s):  
Azdine Benzekri ◽  
Patrick Dubourdeaux ◽  
Jean Marc Latour ◽  
Jean Laugier ◽  
Paul Rey
Keyword(s):  
Magnetic Properties ◽  
Molecular Structures ◽  
Binuclear Copper ◽  
Bridging Ligands

Synthesis and Magnetic Properties of a Planar Binuclear Copper(II) Phthalocyanine Complex

2004 ◽  
Vol 77 (9) ◽  
pp. 1647-1648 ◽  
Author(s):  
Makoto Handa ◽  
Norihito Kataoka ◽  
Yoshifumi Ito ◽  
Takahiro Tonomura ◽  
Ichiro Hiromitsu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Binuclear Copper ◽  
Phthalocyanine Complex

Synthesis, Magnetic Property and Assembly Studies of Two Cu(II) Complexes Based on o-phenanthroline and Phosphate

2021 ◽  
Author(s):  
Fang Fang Jian ◽  
E Liu ◽  
Zesen Jin ◽  
Fangfang Jian
Keyword(s):  
Magnetic Properties ◽  
Phosphoric Acid ◽  
Copper Complexes ◽  
Raw Materials ◽  
Great Influence ◽  
Crystal Structure Analysis ◽  
Supramolecular Interactions ◽  
Metal Phosphate ◽  
Neutral Ligand ◽  
One Pot

Abstract Using newly precipitated Cu(OH)2, o-phenanthroline and phosphoric acid as raw materials, two complicated Cu(II) compounds were obtained by one-pot method. They are double-nuclear Cu(II) 1, {[Cu2(phen)2(H2PO4)3][Cu2(phen)2(H2O)(H2PO4)3]}·2H2PO4·5H2O, and mononuclear Cu(II) 2, [Cu(phen)2(H2PO4)]4·4H3PO4·2HPO4·6H2O. The crystal structure analysis showed that the copper phosphate reacted with the neutral ligand o-phenanthroline to obtain the compounds with different structures. Phosphoric acid can exist in various forms in copper complexes, such as H3PO4, (H2PO4)1-, (HPO4)2-, and form a rich and colorful supramolecular interaction with water molecules. Hirschfeld surface analysis gives the types and regions of molecular interactions in crystals. It is of scientific significance to understand the reaction between transition metal phosphate and organic neutral ligand. The thermogravimetric and magnetic properties of compounds 1 and 2 were also reported. Magnetic analysis shows that supramolecular interactions and dipole-dipole interactions have great influence on the magnetic properties of two compounds. CCDC: 20565681 for 1; 2090334 for 2.

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