ChemInform Abstract: AZABOROLINYL COMPLEXES. VIII. CHEMICAL AND SPECTROSCOPIC STUDIES ON BIS(η-1,2-AZABOROLINYL)IRON COMPLEXES.

1983 ◽  
Vol 14 (25) ◽  
Author(s):  
G. SCHMID ◽  
U. HOEHNER ◽  
D. KAMPMANN ◽  
D. ZAIKA ◽  
R. BOESE
1999 ◽  
Vol 239 (2) ◽  
pp. 227-232 ◽  
Author(s):  
M. Katada ◽  
T. Nawa ◽  
H. Kumagai ◽  
S. Kawata ◽  
S. Kitagawa

1990 ◽  
Vol 49 (2) ◽  
Author(s):  
Hisao Hori ◽  
Koji Kadono ◽  
Kazuki Fukuda ◽  
Hidenari Inoue ◽  
Tsuneo Shirai ◽  
...  

2012 ◽  
Vol 365 ◽  
pp. 012010
Author(s):  
A Mishra ◽  
R Sharma ◽  
B D Shrivastava ◽  
N Mishra

2015 ◽  
Vol 11 ◽  
pp. 2549-2556 ◽  
Author(s):  
David Porter ◽  
Belinda M-L Poon ◽  
Peter J Rutledge

Iron(II) complexes of the tetradentate amines tris(2-pyridylmethyl)amine (TPA) and N,N′-bis(2-pyridylmethyl)-N,N′-dimethylethane-1,2-diamine (BPMEN) are established catalysts of C–O bond formation, oxidising hydrocarbon substrates via hydroxylation, epoxidation and dihydroxylation pathways. Herein we report the capacity of these catalysts to promote C–N bond formation, via allylic amination of alkenes. The combination of N-Boc-hydroxylamine with either FeTPA (1 mol %) or FeBPMEN (10 mol %) converts cyclohexene to the allylic hydroxylamine (tert-butyl cyclohex-2-en-1-yl(hydroxy)carbamate) in moderate yields. Spectroscopic studies and trapping experiments suggest the reaction proceeds via a nitroso–ene mechanism, with involvement of a free N-Boc-nitroso intermediate. Asymmetric induction is not observed using the chiral tetramine ligand (+)-(2R,2′R)-1,1′-bis(2-pyridylmethyl)-2,2′-bipyrrolidine ((R,R′)-PDP).


2002 ◽  
pp. 297-300
Author(s):  
M. Katada ◽  
T. Nawa ◽  
H. Kumagai ◽  
S. Kawata ◽  
S. Kitagawa

2001 ◽  
Vol 40 (21) ◽  
pp. 5324-5333 ◽  
Author(s):  
Hartmut Drechsel ◽  
Marina Fiallo ◽  
Arlette Garnier-Suillerot ◽  
Berthold F. Matzanke ◽  
Volker Schünemann

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