ChemInform Abstract: OPTICALLY ACTIVE ALLYLSILANES. 2. HIGH STEREOSELECTIVITY IN ASYMMETRIC REACTION WITH ALDEHYDES PRODUCING HOMOALLYLIC ALCOHOLS

1982 ◽  
Vol 13 (49) ◽  
Author(s):  
T. HAYASHI ◽  
M. KONISHI ◽  
M. KUMADA
2020 ◽  
Vol 18 (3) ◽  
pp. 479-487 ◽  
Author(s):  
Seda Karahan ◽  
Cihangir Tanyeli

Bifunctional squaramide catalyzed asymmetric Mannich reaction of alpha-azido ketones and isatin derived ketiminines were established for the first time with high stereoselectivity. Adducts are valuable synthons for optically active heterocycles.


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