ChemInform Abstract: THE ELECTROCHEMICAL BEHAVIOR OF COBALT IN ALKALINE SOLUTIONS. PART I. THE POTENTIODYNAMIC RESPONSE IN THE POTENTIAL REGION OF THE COBALT/COBALTOUS OXIDE COUPLE

1982 ◽  
Vol 13 (28) ◽  
Author(s):  
H. GOMEZ MEIER ◽  
J. R. VILCHE ◽  
A. J. ARVIA
2015 ◽  
Vol 228 ◽  
pp. 207-212
Author(s):  
B. Łosiewicz ◽  
Magdalena Popczyk ◽  
A. Budniok

Electrochemical characteristics of the composite Ni-P+TiO2electrocoatings with a differentiated content of TiO2composite component from 14 to 20 at.%, dependent on temperature conditions of electrodeposition from 293 to 333 K, was carried out in an alkaline 2.5 M NaOH solution. Cyclic voltammetry studies of the Ni-P+TiO2coatings and comparable Ni-P electrocatalysts revealed that cyclic cathode-anode polarization activated TiO2as the embedded composite component for the Ni-P+TiO2coating obtained at 333 K only.


2017 ◽  
Vol 231 (6) ◽  
Author(s):  
H. Nady ◽  
M. Negem

AbstractThe present paper deals with evaluation of corrosion behavior of electrodeposited nanocrystalline (Nc) NiCo, NiZn and NiCu alloys. Nc NiCo, NiZn and NiCu coating electrodes were electroplated from sulfate electrolyte on copper foil by the galvanostatic technique and ultrasound waves. The chemical composition, surface morphology and crystalline structure of the different alloys were studied using energy dispersive spectroscopy, scanning electron microscope and X-ray diffraction methods. The electrochemical behavior of the deposited material in 1.0 M KOH solutions was investigated. The electrochemical behavior of the coating electrodes in alkaline solutions was investigated by potentiodynamic polarization techniques and electrochemical impedance spectroscopy (EIS). Results showed that the alloying of nickel with Co causes an increase in the stability of Ni–alloy in alkaline solutions in comparison to Ni–Cu and Ni–Zn alloys. The corrosion resistance values of Ni–Zn coatings were lower compared to those of the other investigated alloy coatings due to preferential dissolution of Zn from the matrix. The experimental impedance data were fitted to theoretical data according to a proposed equivalent circuit model representing the electrode/electrolyte interface.


2006 ◽  
Vol 42 (3) ◽  
pp. 260-264
Author(s):  
E. V. Nikitchenko ◽  
S. A. Kaluzhina ◽  
N. P. Andreeva

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