ChemInform Abstract: SYNTHESIS, REACTIONS, AND CRYSTAL STRUCTURES OF CARBONYL-FREE HYDRIDE-BRIDGED MIXED ORGANOTRANSITION METAL DERIVATIVES OF BIS(PHOSPHINE)RHODIUM(III) OR -IRIDIUM(III) CATIONS WITH DIHYDRIDOBIS(η5-CYCLOPENTADIENYL)MOLYBDENUM AND -TUNGST

1982 ◽  
Vol 13 (25) ◽  
Author(s):  
O. W. HOWARTH ◽  
C. H. MCATEER ◽  
P. MOORE ◽  
G. E. MORRIS ◽  
N. W. ALCOCK
Keyword(s):  
Crystal Structures ◽  
Metal Derivatives ◽  
Synthesis Reactions ◽  
Derivatives Of

N,N′-Bis(silyl)ethylendiamine und 1,3-Diaza-2-silacyclopentane – Synthese, Reaktionen, Strukturen/ N,N′-Bis(silyl)ethylenediamines and 1.3-Diaza-2-silacyclopentanes – Synthesis, Reactions, Crystal Structures

2002 ◽  
Vol 57 (1) ◽  
pp. 99-106 ◽  
Author(s):  
Friedhelm Diedrich ◽  
Christina Ebker ◽  
Uwe Klingebiel ◽  
Clemens Reiche ◽  
Thomas Labahn ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Tert Butyl ◽  
Synthesis Reactions ◽  
Derivatives Of

Ethylenediamine reacts with chlorosilanes to give N,N′-bis(silyl)ethylenediamines [(H2CNHSiRR′R″)2, 3: R, R′ = Me; R″ = CMe3; 4: R = H; R′, R″= CMe3; 5: R,R′ = CMe3, R″ = OH]. In the reaction of N,N,N′-tris(trimethylsilyl)ethylenediamine with SiF4 the difluoro-bis(1.1.4- tris(trimethylsilyl)ethylenediamino)silane (6) is obtained. The 1.3-diaza-2-silacyclopentanes R2Si[N(SiMe2R′)CH2]2, 7 - 10 (7: R = Cl, R′= Ph; 8: R = Cl, R′ = CMe3; 9: R = H, Cl, R′ = CMe3; 10: R = Br, R′ = CMe3) are isolated from the reactions of the corresponding bis(silyl)ethylenediamines and halosilanes in Et2O with NEt3 as HHal acceptor. Dilithium derivatives of N,N′-bis(silyl)ethylenediamines react with fluorosilanes with formation of the 1.3-diaza-2-silacyclopentanes, R2Si[N(SiMe2R′)CH2]2 (11 - 13) (11: R = F,R′ =Me; 12: R = F, R′ = CMe3; 13: R = CHMe2, R′ = Me). N-Fluoro-di(tert-butyl)silyl-N,N′-bis(trimethylsilyl)- ethylenediamine (14) is formed in the reaction of lithiated bis(trimethylsilyl)ethylenediamine with F2Si(CMe3)2. 8 reacts in amolar ratio 1:2 withNaNH2 or NaOMe with formation of 15 and 16, respectively · R2Si[N(SiMe2CMe3)CH2]2, 15: R = NH2; 16: R = OMe]. 1.3-Bis(tert-butyldimethylsilyl)- 2-tert-butyldimethylsiloxy-2-fluoro-1.3-diaza-2-silacyclopentane is the product of the reaction of 12 with LiOSiMe2CMe3. The crystal structures of 6 and 13 have been determined.

scholarly journals Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 199-227
Author(s):  
Young Hoon Lee ◽  
Jee Young Kim ◽  
Sotaro Kusumoto ◽  
Hitomi Ohmagari ◽  
Miki Hasegawa ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Weak Interactions ◽  
Dispersion Interactions ◽  
Derivatives Of

Analysis of the weak interactions within the crystal structures of 33 complexes of various 4′-aromatic derivatives of 2,2′:6′,2″-terpyridine (tpy) shows that interactions that exceed dispersion are dominated, as expected, by cation⋯anion contacts but are associated with both ligand–ligand and ligand–solvent contacts, sometimes multicentred, in generally complicated arrays, probably largely determined by dispersion interactions between stacked aromatic units. With V(V) as the coordinating cation, there is evidence that the polarisation of the ligand results in an interaction exceeding dispersion at a carbon bound to nitrogen with oxygen or fluorine, an interaction unseen in the structures of M(II) (M = Fe, Co, Ni, Cu, Zn, Ru and Cd) complexes, except when 1,2,3-trimethoxyphenyl substituents are present in the 4′-tpy.

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