ChemInform Abstract: THE IRON SULFIDE (FE1-XS)-LEAD SULFIDE (PBS)-ZINC SULFIDE PHASE SYSTEM

1980 ◽  
Vol 11 (32) ◽  
Author(s):  
J. E. DUTRIZAC
ChemInform ◽  
2010 ◽  
Vol 22 (14) ◽  
pp. no-no
Author(s):  
V. VESELY ◽  
M. HARTMAN ◽  
K. SVOBODA ◽  
J. MRACEK

2005 ◽  
Author(s):  
Thomas Henry Lopez ◽  
Mingdong Yuan ◽  
Danny Andy Williamson ◽  
John L. Przybylinski
Keyword(s):  

2014 ◽  
Vol 14 (9) ◽  
pp. 4295-4302 ◽  
Author(s):  
Pengpeng Bai ◽  
Shuqi Zheng ◽  
Changfeng Chen ◽  
Hui Zhao

2019 ◽  
Author(s):  
Bader Alharbi ◽  
Norah Aljeaban ◽  
Alexander Graham ◽  
Kenneth S. Sorbie

1958 ◽  
Vol 31 (3) ◽  
pp. 624-630
Author(s):  
Yuji Minoura

Abstract 1. Both mercaptides and disulfides were obtained by the reactions between benzyl mercaptan or tolyl mercaptan with zinc oxide or lead oxide. Qualitatively, mercaptides were formed from benzyl mercaptan easier than from tolyl mercaptan, and lead oxide reacted with mercaptan easier than zinc oxide with mercaptan. From the fact that no metallic sulfide was present, disulfides were likely formed from the oxidation of mercaptans by air. 2. The mono- or disulfides of the benzyl and tolyl series did not react with zinc oxide or lead oxide. 3. Neither tolyl tri- nor tetrasulfide reacted with zinc oxide, but benzyl tri- and tetrasulfide reacted with zinc oxide to give zinc sulfide. In the case of benzyl trisulfide, hydrogen sulfide, stilbene and benzaldehyde were formed, and in the case of tetrasulfide, we found the formation of hydrogen sulfide, stilbene, benzaldehyde and sulfur. 4. The tri- and tetrasulfide of both the benzyl and tolyl series reacted with lead oxide and they gave lead sulfide and organic disulfide. That is, they were desulfurized by lead oxide. In these reactions the benzyl series was more reactive than the tolyl series and the tetrasulfide was more reactive than trisulfide in the same series. 5. Lead oxide reacted with polysulfide easier than zinc oxide. 6. From the results of reactions between metallic oxide with mercaptan or other sulfide, it was concluded that the vulcanization mechanism of polysulfide rubber by metallic oxide is the reaction represented by Equations (1) to (4), the products being converted to high polymer without formation of a network of polysulfides.


2010 ◽  
Vol 148-149 ◽  
pp. 1404-1407
Author(s):  
Ya Hui Zhang ◽  
Xi Cheng ◽  
Qing Wang

A low-temperature precursor sulfuration route has been established to prepare metal sulfides with different nanostructures during the synthesis of nickel sulfide. The advantages of the low-temperature precursor sulfuration route were testified by the synthesis of different metal sulfides ( lead sulfide, zinc sulfide and cobalt sulfide). It offers a novel path to the preparation of other metal sulfides.


Author(s):  
Thao A. Nguyen

It is well known that the large deviations from stoichiometry in iron sulfide compounds, Fe1-xS (0≤x≤0.125), are accommodated by iron vacancies which order and form superstructures at low temperatures. Although the ordering of the iron vacancies has been well established, the modes of vacancy ordering, hence superstructures, as a function of composition and temperature are still the subject of much controversy. This investigation gives direct evidence from many-beam lattice images of Fe1-xS that the 4C superstructure transforms into the 3C superstructure (Fig. 1) rather than the MC phase as previously suggested. Also observed are an intrinsic stacking fault in the sulfur sublattice and two different types of vacancy-ordering antiphase boundaries. Evidence from selective area optical diffractograms suggests that these planar defects complicate the diffraction pattern greatly.


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