ChemInform Abstract: ION-SELECTIVE ELECTRODES WITH SENSORS OF ELECTROLYTICALLY PLATED CHALCOGENIDE COATINGS. PART I. COPPER ION-SELECTIVE ELECTRODE BASED ON PLATED COPPER SELENIDE

1979 ◽  
Vol 10 (52) ◽  
Author(s):  
M. NESHKOVA ◽  
H. SHEYTANOV
2018 ◽  
Vol 52 (2) ◽  
pp. 353-362
Author(s):  
Wen Liu ◽  
Jiahua Huang ◽  
Yiming Zhu ◽  
Huan Zhang ◽  
Ning Ning ◽  
...  

1974 ◽  
Vol 57 (5) ◽  
pp. 1205-1208
Author(s):  
Norio Hazemoto ◽  
Naoki Kamo ◽  
Yonosuke Kobatake

Abstract An ion-selective electrode responsive to saccharin was made by dissolving an ion association which exists between iron(II)-bathophenanthroline chelate and saccharin in nitrobenzene. The electrode developed was capable of measuring saccharin ion concentration in the presence of other sweetening substances, e.g., saccharose, glucose, sodium cyclamate, and sorbitol, over the concentration range of 10-1 to 10-5M.


1974 ◽  
Vol 20 (9) ◽  
pp. 1217-1221 ◽  
Author(s):  
Jack A Lustgarten ◽  
Robert E Wenk ◽  
Charles Byrd ◽  
Barbara Hall

Abstract An automated analyzer, in which ion-selective electrodes are used to measure sodium, potassium, and chloride in serum, was assessed in a clinical setting. Day-to-day precision, evaluated by replicate analysis of serum pools, yielded the following coefficients of variation for sodium, potassium, and chloride, respectively: 0.99%, 1.39%, and 0.67%. Values for chloride in both commercial control sera and aqueous standards were linearly related to concentration over a range of at least 10-220 mmol/liter; however, results with the potassium and sodium electrodes showed slight curvilinearity over the range 0-24 and 10-220 mmol/liter, respectively. Mean recoveries for sodium, potassium, and chloride for concentrations covering the clinically important ranges were 98.3-102.3%, 95.9-100.0%, and 97.8-102.0%. The only important differences between experimental and comparison methods in sera were falsely high values obtained with the ion-selective electrode for K+ (caused by supranormal ammonia concentrations) and for Cl- (caused by administered bromide). Mean sodium and chloride values obtained with the electrode did not differ significantly from values obtained by flame-emission photometry or coulometry for duplicate patients’ specimens, but potassium values did differ slightly (P = .05).


1970 ◽  
Vol 7 (7) ◽  
pp. 19-23 ◽  
Author(s):  
A Rajbhandari ◽  
AP Yadav ◽  
K Manandhar ◽  
RR Pradhananga

The polycrystalline materials obtained by co-precipitation of silver sulphide and appropriate silver halide are used to prepare silver sulphide based membrane electrodes selective to the silver, chloride, bromide, iodide, and sulphide ions. The powder materials are characterized by x-ray diffraction, SEM equipped with EDAX. These membrane electrodes are found to give Nernstian response with the appropriate ions in the concentration range from 1x10-1 to 1x10-5 M. The performance of these home made electrodes is at par with the commercial electrodes. The electrodes have been successfully used for the quantitative determination of chloride, bromide iodide, silver, and sulphide ions and also for the determination of thiamine in pharmaceutical preparations. For developing countries like Nepal, who can not afford to procure high cost commercial ion selective electrodes, these home made ion selective electrodes are especially appealing since the electrode can be fabricated with ease in low cost and the electrode is well behaved and sufficiently accurate for the analysis with ion selective electrodes. Key words: Ion selective electrode; Home made ion selective electrode; Silver sulphide; Thiamine; Vitamin B1. DOI: 10.3126/sw.v7i7.3818 Scientific World Vol.7(7) 2009 pp.19-23  


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