ChemInform Abstract: PHOSPHINERHODIUM COMPLEXES AS HOMOGENEOUS CATALYSTS. X. HOMOGENEOUS HYDROGENATION OF KETONES USING PHOSPHINERHODIUM CATALYSTS MODIFIED WITH TRIETHYLAMINE

1979 ◽  
Vol 10 (48) ◽  
Author(s):  
B. HEIL ◽  
S. TOEROES ◽  
J. BAKOS ◽  
L. MARKO
Keyword(s):  
Homogeneous Hydrogenation ◽  
Homogeneous Catalysts

Rhodium(I) and (III) Complexes of Some Phospholes and Their Behavior as Homogeneous Hydrogenation Catalysts

1972 ◽  
Vol 50 (22) ◽  
pp. 3714-3718 ◽  
Author(s):  
David G. Holah ◽  
Alan N. Hughes ◽  
Benjamin C. Hui
Keyword(s):  
Homogeneous Hydrogenation ◽  
Homogeneous Catalysts ◽  
Hydrogenation Catalysts ◽  
Chloride Hydrate

Reactions between rhodium(III) chloride hydrate and certain phospholes are described; these result in the formation of both Rh (III) and Rh (I) complexes. The phospholes also react with Rh (I) carbonyl and ethylene complexes. The products of these reactions were investigated as homogeneous catalysts in the hydrogenation of 1-hexene, and some show relative rates of hydrogenation comparable with that of hydridocarbonyltris(triphenylphosphine)rhodium(I) but slower than that of tris(triphenylphosphine)rhodium (I) chloride.

Ligand Tethering by Ion-Exchange for the Immobilization of Homogeneous Catalysts

2012 ◽  
Vol 1 (2) ◽  
pp. 100-106 ◽  
Author(s):  
I. Such-Basanez ◽  
C. Salinas-Martinez de Lecea ◽  
M. C. Roman-Martinez
Keyword(s):  
Ion Exchange ◽  
Homogeneous Catalysts

Get Rid of the Shackle from Supports: Construct Recoverable Semi-Homogeneous Catalysts with Attapulgite

2021 ◽  
Author(s):  
Ruixiang Guo ◽  
Gang Wang ◽  
Wei Liu ◽  
Zibei Yao ◽  
Wei-Sheng Liu
Keyword(s):  
Catalytic Activity ◽  
Homogeneous Catalysts ◽  
Immobilized Catalyst ◽  
Novel Strategy ◽  
Adsorption Desorption

Traditionally, the immobilized catalyst sacrifices a part of catalytic activity for its recyclability. To reproduce the catalytic activity of active specie, we construct a novel strategy called "adsorption-desorption-adsorption". Since the...

Encapsulation of Homogeneous Catalysts in Mesoporous Materials Using Diffusion-Limited Atomic Layer Deposition

2017 ◽  
Vol 57 (4) ◽  
pp. 1091-1095 ◽  
Author(s):  
Shufang Zhang ◽  
Bin Zhang ◽  
Haojie Liang ◽  
Yequn Liu ◽  
Yan Qiao ◽  
...  
Keyword(s):  
Atomic Layer Deposition ◽  
Mesoporous Materials ◽  
Atomic Layer ◽  
Homogeneous Catalysts ◽  
Diffusion Limited ◽  
Layer Deposition
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