ChemInform Abstract: MASS SPECTROMETRIC STUDIES ON COPPER AND SILVER HALIDES. PART IV. SYSTEMS SILVER COPPER CHLORIDE (AGXCU1-XCL) (0 ≤ X ≤ 1) AND SILVER CHLORIDE BROMIDE (AGCLXBR1-X) (0 ≤ X ≤ 1)

1979 ◽  
Vol 10 (37) ◽  
Author(s):  
O. BERNAUER ◽  
B. BUSSE ◽  
K. G. WEIL
Keyword(s):  
Silver Chloride ◽  
Copper Chloride ◽  
Mass Spectrometric ◽  
Silver Halides ◽  
Silver Copper

Behavior of a sulfur vapor electrode in sulfide melts

1968 ◽  
Vol 46 (10) ◽  
pp. 1611-1620 ◽  
Author(s):  
W. T. Thompson ◽  
S. N. Flengas
Keyword(s):  
Thermodynamic Properties ◽  
Silver Chloride ◽  
Cell Voltage ◽  
Silver Sulfide ◽  
Mass Spectrometric ◽  
Sulfur Vapor ◽  
Sulfur Species ◽  
Mass Spectrometric Data ◽  
Spectrometric Data ◽  
Partial Pressures

The reversible potentials for the formation cell[Formula: see text]have been measured for concentrations of silver sulfide in silver chloride up to 12 mole %, in the temperature range 490 to 860 °C. Nernst behavior with respect to the partial pressures of the various sulfur species present in the vapor phase over the electrode is observed in the range 10−3 to 1.0 atm. Calculations of partial pressures are based on existing mass spectrometric data. The concentration dependence of the cell voltage follows the Nernst law only in very dilute silver sulfide solutions. The data are used to calculate the thermodynamic properties of silver sulfide in solution with silver chloride.

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