ChemInform Abstract: A3ΠI AND B3Σ-EXCITED STATES OF THE SULFINYL RADICAL. PART 1. LASER-INDUCED FLUORESCENCE STUDY OF THE A-X SYSTEM. EXCITATION SPECTRA AND LIFETIMES

1979 ◽  
Vol 10 (35) ◽  
Author(s):  
M. A. A. CLYNE ◽  
I. S. MCDERMID
Keyword(s):  
Excited States ◽  
Laser Induced Fluorescence ◽  
Fluorescence Study ◽  
Excitation Spectra ◽  
Sulfinyl Radical

Laser‐induced fluorescence study of the reaction C(3P)+HI→CH(X 2Π)+I at 300 K

1986 ◽  
Vol 84 (9) ◽  
pp. 5213-5214 ◽  
Author(s):  
Nobuaki Nishiyama ◽  
Hiroshi Sekiya ◽  
Yukio Nishimura
Keyword(s):  
Laser Induced Fluorescence ◽  
Fluorescence Study

scholarly journals Photochemical R2PI study of chirality and intermolecular forces in supersonic beam

2001 ◽  
Vol 3 (4) ◽  
pp. 223-227 ◽  
Author(s):  
A. Giardini Guidoni ◽  
S. Piccirillo ◽  
D. Scuderi ◽  
M. Satta ◽  
T. M. Di Palma ◽  
...  
Keyword(s):  
Excited States ◽  
Molecular Beam ◽  
Intermolecular Forces ◽  
Excitation Spectra ◽  
Supersonic Molecular Beam ◽  
Spectral Shifts ◽  
Band Origin ◽  
Solvent Molecules ◽  
The One ◽  
Diastereomeric Complexes

One and two-color, mass selected R2PI spectra of theS1←S0transitions in the bare(+)-(R)- 1-phenyl-1-ethanol(ER) and its complexes with different solvent molecules (solv) (-)-(R)-2-butanol(BR) or(+)-(S)-2-butanol(BS), (—)-(R)-2-pentanol (TR) or(+)-(S)-2-pentanol(TS) and(-)-(R)-2-butylamine(AR) or(+)-(S)-2-butylamine(AS), have been recorded after a supersonic molecular beam expansion. The one-color R2PI excitation spectra of the diastereomeric complexes are characterized by significant shifts of their band origin relative to that of bareER. The extent and the direction of these spectral shifts are found to depend upon the structure and the configuration ofsolvand are attributed to different short-range interactions in the ground and excited states of the complexes. In analogy with other diastereomeric complexes, the phenomenological binding energy of the homochiral cluster is found to be greater than that of the heterochiral one. Preliminary measurements of excitation spectrum of(+)-(R)-1-Indanol(IR) is also reported.

Laser-Induced Fluorescence Excitation Spectra oftert-Butoxy and 2-Butoxy Radicals

1999 ◽  
Vol 103 (41) ◽  
pp. 8207-8212 ◽  
Author(s):  
Chuji Wang ◽  
Liat G. Shemesh ◽  
Wei Deng ◽  
Michael D. Lilien ◽  
Theodore S. Dibble
Keyword(s):  
Laser Induced Fluorescence ◽  
Excitation Spectra ◽  
Fluorescence Excitation ◽  
Fluorescence Excitation Spectra
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