ChemInform Abstract: PHOSPHORUS-CONTAINING INTERMEDIATE PRODUCTS AND DYES. IV. PHOSPHORUS-CONTAINING PHENOLS. KINETICS OF THE REACTIONS OF DIALKYL-(4-CHLOROPHENYL)PHOSPHINE OXIDES WITH SODIUM METHOXIDE IN METHANOL

1979 ◽  
Vol 10 (33) ◽  
Author(s):  
V. V. KORMACHEV ◽  
T. V. VASIL'EVA ◽  
K. V. SOLODOVA ◽  
O. T. ALEKSEEVA ◽  
V. A. KUKHTIN
Keyword(s):  
Sodium Methoxide ◽  
Phosphine Oxides ◽  
Intermediate Products ◽  
Phosphorus Containing ◽  
Kinetics Of

Kinetics of the reaction between boron trifluoride methanol complex and sodium methoxide to produce enriched 10B methylborate

2016 ◽  
Vol 22 (2) ◽  
pp. 139-143 ◽  
Author(s):  
Wuke Lang ◽  
Weijiang Zhang ◽  
Yin Tang ◽  
Jiao Xu ◽  
Lei Zhang
Keyword(s):  
Sodium Methoxide ◽  
Boron Trifluoride ◽  
Kinetics Of

Kinetics Study of Thermal Degradation of Epoxy Resins Modified with 2-(Diphenylphosphinyl)-1, 4-Benzenediol

2014 ◽  
Vol 1053 ◽  
pp. 240-244
Author(s):  
Xiu Juan Tian ◽  
Zhong Wei Wang ◽  
Jun Gao
Keyword(s):  
Thermal Degradation ◽  
Epoxy Resins ◽  
Phosphorus Content ◽  
Degradation Kinetics ◽  
Thermal Degradation Kinetics ◽  
Ozawa Method ◽  
Air Atmosphere ◽  
Phosphorus Containing ◽  
Modified Epoxy ◽  
Kinetics Of

Phosphorus-containing epoxy resins with different phosphorus content were obtained from 2-(Diphenylphosphinyl)-1, 4-benzenediol (DPO-HQ) and biphenyl-A epoxy resin by crosslinking with 4, 4’-diaminodiphenylsulfone (DDS). The thermal degradation kinetics of the modified epoxy resins containing different phosphorus content were investigated by dynamic thermogravimetric analysis (TGA) under air atmosphere with different heating rate. The degradation of epoxy resins containing flame retardant components were found to be changed. The additive of phosphorus increases the carbon residue and improves the thermal stability at elevated temperature. The kinetics of thermal degradation was evaluated by Kissinger method and Flynn-Wall-Ozawa method, which do not require knowledge of the reaction mechanism. The results showed that the activation energies at lower degree of the degradation decreased with increasing of phosphorus content, while increased at higher degree of the degradation.

Adsorption kinetics of alkyl phosphine oxides in water/alkane systems with transfer across the interface

1997 ◽  
Vol 105 (1) ◽  
pp. 346-350 ◽  
Author(s):  
F. Ravera ◽  
M. Ferrari ◽  
L. Liggieri ◽  
R. Miller
Keyword(s):  
Adsorption Kinetics ◽  
Phosphine Oxides ◽  
Kinetics Of

Acridone studies. XIV. The selective demethylation of 2,3-Dimethoxy-10-methyl-9-oxoacridine-1,4-quinone by base

1975 ◽  
Vol 28 (6) ◽  
pp. 1351 ◽  
Author(s):  
JR Cowan ◽  
DKC Hodgeman ◽  
RH Prager
Keyword(s):  
Sodium Hydroxide ◽  
Sodium Methoxide ◽  
Reaction Pathways ◽  
Methoxyl Group ◽  
Product Composition ◽  
Relative Extent ◽  
Kinetics Of

The selective demethylation of 2,3-dimethoxy-10-methyl-9-oxoacridine- 1,4-quinone by sodium hydroxide has been studied by following the change in product composition with hydroxide concentration, by measuring the relative extent of exchange at C2 and C3 with sodium methoxide[T], and by following the kinetics of the reaction in alkali. Reaction pathways are proposed to rationalize the observation that the C2 methoxyl group is replaced more readily in dilute alkali or on warming, but the C 3 methoxyl group is replaced in more concentrated alkali.

Kinetics of thermal oxidative degradation of phosphorus-containing flame retardant copolyesters

2002 ◽  
Vol 76 (3) ◽  
pp. 401-409 ◽  
Author(s):  
Bo Wu ◽  
Yu-Zhong Wang ◽  
Xiu-Li Wang ◽  
Ke-Ke Yang ◽  
Yong-Dong Jin ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Oxidative Degradation ◽  
Thermal Oxidative Degradation ◽  
Phosphorus Containing ◽  
Kinetics Of
Sign in / Sign up

Export Citation Format

Share Document