ChemInform Abstract: ELECTRONIC STRUCTURE OF HIGHLY SYMMETRICAL COMPOUNDS OF THE FLUORINE GROUP ELEMENTS. XI. ELECTRONIC RAMAN SPECTRUM AND CRYSTAL FIELD SPLITTING PATTERN OF THE 3H4 GROUND STATE MULTIPLICITY OF DICESIUM POTASSIUM PRASEODYMIUM HEXAFLUORID

1979 ◽  
Vol 10 (14) ◽  
Author(s):  
H.-D. AMBERGER
Keyword(s):  
Electronic Structure ◽  
Raman Spectrum ◽  
Crystal Field ◽  
Ground State ◽  
Crystal Field Splitting ◽  
Field Splitting ◽  
State Multiplicity

Crystal Field Splitting of the Ground State of Terbium(III) and Dysprosium(III) Complexes with a Triimidazolyl Tripod Ligand and an Acetate Determined by Magnetic Analysis and Luminescence

2014 ◽  
Vol 53 (19) ◽  
pp. 10359-10369 ◽  
Author(s):  
Seira Shintoyo ◽  
Keishiro Murakami ◽  
Takeshi Fujinami ◽  
Naohide Matsumoto ◽  
Naotaka Mochida ◽  
...  
Keyword(s):  
Crystal Field ◽  
Ground State ◽  
Crystal Field Splitting ◽  
Field Splitting ◽  
Magnetic Analysis

Theory Of 3d Transition Metal Defects In 3C SiC

1996 ◽  
Vol 442 ◽  
Author(s):  
Harald Overhof
Keyword(s):  
Electronic Structure ◽  
Transition Metal ◽  
Electronic Properties ◽  
Crystal Field ◽  
High Spin ◽  
Crystal Field Splitting ◽  
Large Crystal ◽  
Field Splitting ◽  
Vacancy Model ◽  
The Difference

AbstractThe electronic properties of 3d transition metal (TM) defects located on one of the four different tetrahedral positions in 3C SiC are shown to be quite site-dependent. We explain the differences for the 3d TMs on the two substitutional sites within the vacancy model: the difference of the electronic structure between the carbon vacancy VC and the silicon vacancy VSi is responsible for the differences of the 3d TMs. The electronic properties of 3d TMs on the two tetrahedral interstitial sites differ even more: the TMs surrounded tetrahedrally by four Si atoms experience a large crystal field splitting while the tetrahedral C environment does not give rise to a significant crystal field splitting at all. It is only in the latter case that high-spin configurations are predicted.

Large Ground-State and Excited-State Crystal Field Splitting of 8-fold-Coordinate Cm3+in [Y(H2O)8]Cl3·15-crown-5

2006 ◽  
Vol 110 (11) ◽  
pp. 5279-5285 ◽  
Author(s):  
Patric Lindqvist-Reis ◽  
Clemens Walther ◽  
Reinhardt Klenze ◽  
Andreas Eichhöfer ◽  
Thomas Fanghänel
Keyword(s):  
Excited State ◽  
Crystal Field ◽  
Ground State ◽  
Crystal Field Splitting ◽  
Field Splitting
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