ChemInform Abstract: TOTAL SYNTHESIS OF PROSTAGLANDIN F2α BY CHIRALITY TRANSFER FROM D-GLUCOSE

1979 ◽  
Vol 10 (13) ◽  
Author(s):  
G. STORK ◽  
T. TAKAHASHI ◽  
I. KAWAMOTO ◽  
T. SUZUKI
Keyword(s):  
Total Synthesis ◽  
Prostaglandin F2α ◽  
Chirality Transfer

Total Synthesis of Prostaglandin F2α via Nickel-Promoted Stereoselective Cyclization of 1,3-Diene and Aldehyde

Synlett ◽  
1997 ◽  
Vol 1997 (6) ◽  
pp. 734-736 ◽  
Author(s):  
Yoshihiro Sato ◽  
Masanori Takimoto ◽  
Miwako Mori
Keyword(s):  
Total Synthesis ◽  
Prostaglandin F2α

Golden opportunities in catalysis

2008 ◽  
Vol 80 (5) ◽  
pp. 1063-1069 ◽  
Author(s):  
Norbert Krause ◽  
Volker Belting ◽  
Carl Deutsch ◽  
Jörg Erdsack ◽  
Hong-Tao Fan ◽  
...  
Keyword(s):  
Natural Products ◽  
Total Synthesis ◽  
High Reactivity ◽  
Donor Ligands ◽  
Cyclization Product ◽  
Chirality Transfer ◽  
Key Features ◽  
Stereogenic Center

The gold-catalyzed endo-cycloisomerization of allenes bearing nucleophilic substituents in the α- or β-position opens up a versatile access to various five- and six-membered heterocycles. Key features of these transformations are the high reactivity of the allene in the presence of Lewis-acidic, carbophilic gold(I) or gold(III) catalysts, and the chirality transfer from the allenic axis of chirality to the new stereogenic center in the cyclization product. Recent contributions of our group include the optimization of chirality transfer by using σ-donor ligands to gold, and applications in the total synthesis of natural products, e.g., of the β-carboline alkaloids (-)-isocyclocapitelline and (-)-isochrysotricine.

ChemInform Abstract: TOTAL SYNTHESIS OF PROSTAGLANDIN-F2α INVOLVING STEREOCONTROLLED AND PHOTO-INDUCED REACTIONS OF BICYCLO(3.2.0)HEPTANONES

1980 ◽  
Vol 11 (25) ◽  
Author(s):  
C. C. HOWARD ◽  
R. F. NEWTON ◽  
D. P. REYNOLDS ◽  
A. H. WADSWORTH ◽  
D. R. KELLY ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Prostaglandin F2α

Asymmetric Total Synthesis of (+)-Brefeldin A from (S)-Lactate by Triple Chirality Transfer Process and Nitrile Oxide Cycloaddition†,1

2002 ◽  
Vol 67 (3) ◽  
pp. 764-771 ◽  
Author(s):  
Deukjoon Kim ◽  
Jongkook Lee ◽  
Phil Jong Shim ◽  
Joong Inn Lim ◽  
Hyunil Jo ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Transfer Process ◽  
Brefeldin A ◽  
Nitrile Oxide ◽  
Asymmetric Total Synthesis ◽  
Chirality Transfer
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