ChemInform Abstract: STUDIES ON TRANSITION METAL CYANO COMPLEXES. PART 2. UNSUBSTITUTED CYANORHENATES, (RE(CN)X)N-, AND CYANORHENATES WITH THIO-, SELENO-, AND NITROSYL LIGANDS

1978 ◽  
Vol 9 (52) ◽  
Author(s):  
W. P. GRIFFITH ◽  
P. M. KIERNAN ◽  
J.-M. BREGEAULT
Keyword(s):  
Transition Metal ◽  
Cyano Complexes

Transition metal-cyano complexes in molten potassium cyanide

1969 ◽  
Vol 8 (11) ◽  
pp. 2499-2503 ◽  
Author(s):  
Jesse G. Reinstein ◽  
Ernest Griswold ◽  
Jacob Kleinbert
Keyword(s):  
Transition Metal ◽  
Potassium Cyanide ◽  
Cyano Complexes

Carbon-13/carbon-12 isotope effects on nitrogen-15 chemical shielding in some diamagnetic cyano complexes

1982 ◽  
Vol 60 (17) ◽  
pp. 2194-2197 ◽  
Author(s):  
Roderick E. Wasylishen
Keyword(s):  
Transition Metal ◽  
High Field ◽  
Chemical Shifts ◽  
Isotope Effects ◽  
Chemical Shielding ◽  
Cyanide Ion ◽  
Theoretical Formulation ◽  
Metal Cyanides ◽  
Shielding Constants ◽  
Cyano Complexes

Carbon-13/carbon-12 isotope-induced 15N chemical shifts of 0.06 to 0.10 ppm have been observed for the cyanide ion and several transition metal cyanides. In each case, the 15N resonance of the 13C labelled isotopomers is to high field of that in the corresponding carbon-12 species. The sensitivity of the 15N and 13C shielding constants in the cyanide ion to small changes in the CN bond length are evaluated using the theoretical formulation of Jameson: (∂σ(15N)/∂r)e = −872 ± 160 ppm/Å and (∂σ(13C)/∂r)e = −473 ± 90 ppm/Å. Nitrogen-15 chemical shifts in the metal complexes exhibit basically the same behaviour as do the 13C chemical shifts in these same complexes.

Reactions of Some Transition Metal Cyano Complexes in Molten Potassium Cyanide

1964 ◽  
Vol 3 (1) ◽  
pp. 88-93 ◽  
Author(s):  
W. L. Magnuson ◽  
Ernest Griswold ◽  
Jacob Kleinberg
Keyword(s):  
Transition Metal ◽  
Potassium Cyanide ◽  
Cyano Complexes
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