ChemInform Abstract: SOLUTIONS OF LITHIUM SALTS IN LIQUID LITHIUM: PREPARATION AND X-RAY CRYSTAL STRUCTURE OF THE DILITHIUM SALT OF CARBODIIMIDE (CYANAMIDE)

1978 ◽  
Vol 9 (52) ◽  
Author(s):  
M. G. DOWN ◽  
M. J. HALEY ◽  
P. HUBBERSTEY ◽  
R. J. PULHAM ◽  
A. E. THUNDER
Keyword(s):  
Crystal Structure ◽  
Liquid Lithium ◽  
Lithium Salts ◽  
X Ray

Substitutionsreaktionen am Niobtetrafluorid-Komplex (η5-C5Me5)NbF4 / Substitution Reactions on the Tetrafluoro Niobium Complex (η5-C5Me5)NbF4

1990 ◽  
Vol 45 (4) ◽  
pp. 423-426 ◽  
Author(s):  
Yuming Xu ◽  
Herbert W. Roesky ◽  
Frank Schrumpf ◽  
Mathias Noltemeyer
Keyword(s):  
Crystal Structure ◽  
Lithium Salts ◽  
Chelate Complexes ◽  
Substitution Reactions ◽  
X Ray

Cp*NbF4 (1) (Cp* = η5-C5Me5) reacts with lithium salts of β-diketones under elimination of LiF to form the chelate complexes (2) and (3). The X-ray crystal structure of 3 was investigated and is compared with the homologous tantalum compound.

Substitutionsreaktionen am Tetrafluorotantal-Komplex (η5-C5Me5)—TaF4 / Substitution Reactions at the Tetrafluorotantalum Complex (η5-C5Me5)—TaF4

1989 ◽  
Vol 44 (11) ◽  
pp. 1369-1372 ◽  
Author(s):  
Herbert W. Roesky ◽  
Frank Schrumpf ◽  
Mathias Noltemeyer
Keyword(s):  
Crystal Structure ◽  
Lithium Salts ◽  
Substitution Reactions ◽  
Distorted Octahedral Environment ◽  
X Ray ◽  
Coordination Site ◽  
Octahedral Environment ◽  
Distorted Octahedral

Cp*TaF4 (1) (Cp* = η5-C5Me5) reacts with lithium salts of benzamidines or 1,3-diketones to form hexa-coordinated complexes of composition Cp*TaF3[(Me3SiN)2CPh] (2), Cp*TaF3[(Me3SiN)2C(p-CF3C6H4)] (3) and Cp*TaF3(O=CPhCH=CPhO) (4). The reactions proceed under elimination of LiF. The X-ray crystal structure of Cp*TaF3(O=CPhCH=CPhO) (4) has been determined shows tantalum to have a distorted octahedral environment, if the Cp* ligand is considered to occupy one coordination site.

ChemInform Abstract: SYNTHESIS OF THE DILITHIUM SALT OF CYANAMIDE IN LIQUID LITHIUM, X-RAY CRYSTAL STRUCTURE OF LI2NCN

1978 ◽  
Vol 9 (21) ◽  
Author(s):  
M. G. DOWN ◽  
M. J. HALEY ◽  
P. HUBBERSTEY ◽  
R. J. PULHAM ◽  
A. E. THUNDER
Keyword(s):  
Crystal Structure ◽  
Liquid Lithium ◽  
X Ray

Synthesis of the dilithium salt of cyanamide in liquid lithium; X-ray crystal structure of Li2NCN

1978 ◽  
pp. 52 ◽  
Author(s):  
Michael G. Down ◽  
Martin J. Haley ◽  
Peter Hubberstey ◽  
Richard J. Pulham ◽  
Anne E. Thunder
Keyword(s):  
Crystal Structure ◽  
Liquid Lithium ◽  
X Ray

A study on α-RuCl3 crystal structure by scanning tunneling microscopy

1989 ◽  
Vol 47 ◽  
pp. 30-31
Author(s):  
H.-J. Cantow ◽  
H. Hillebrecht ◽  
S. Magonov ◽  
H. W. Rotter ◽  
G. Thiele
Keyword(s):  
Crystal Structure ◽  
Density Distribution ◽  
Scanning Tunneling Microscopy ◽  
Electron Density ◽  
Structure Determination ◽  
Electron Density Distribution ◽  
Scanning Tunneling ◽  
Monoclinic Space Group ◽  
Tunneling Microscopy ◽  
X Ray

From X-ray analysis, the conclusions are drawn from averaged molecular informations. Thus, limitations are caused when analyzing systems whose symmetry is reduced due to interatomic interactions. In contrast, scanning tunneling microscopy (STM) directly images atomic scale surface electron density distribution, with a resolution up to fractions of Angstrom units. The crucial point is the correlation between the electron density distribution and the localization of individual atoms, which is reasonable in many cases. Thus, the use of STM images for crystal structure determination may be permitted. We tried to apply RuCl3 - a layered material with semiconductive properties - for such STM studies. From the X-ray analysis it has been assumed that α-form of this compound crystallizes in the monoclinic space group C2/m (AICI3 type). The chlorine atoms form an almost undistorted cubic closed package while Ru occupies 2/3 of the octahedral holes in every second layer building up a plane hexagon net (graphite net). Idealizing the arrangement of the chlorines a hexagonal symmetry would be expected. X-ray structure determination of isotypic compounds e.g. IrBr3 leads only to averaged positions of the metal atoms as there exist extended stacking faults of the metal layers.

X-ray Crystal Structure of ?9-THC-tosylate

Planta Medica ◽  
2008 ◽  
Vol 74 (03) ◽  
Author(s):  
W Gul ◽  
P Carvalho ◽  
D Slade ◽  
M Avery ◽  
JR Duchek ◽  
...  
Keyword(s):  
Crystal Structure ◽  
X Ray

Crystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(–)-1-phenyl-ethyl ammonium percholorate

2003 ◽  
Vol 218 (5) ◽  
Author(s):  
Süheyla Özbey ◽  
F. B. Kaynak ◽  
M. Toğrul ◽  
N. Demirel ◽  
H. Hoşgören
Keyword(s):  
Crystal Structure ◽  
Inclusion Complex ◽  
Single Crystal ◽  
X Ray Diffraction ◽  
Space Group ◽  
X Ray ◽  
New Type

AbstractA new type of inclusion complex, S(–)-1 phenyl ethyl ammonium percholorate complex of R-(–)-2-ethyl - N - benzyl - 4, 7, 10, 13 - tetraoxa -1- azacyclopentadecane, has been prepared and studied by NMR, IR and single crystal X-ray diffraction techniques. The compound crystallizes in space group

Single Crystal Growth of High-Pressure Phases of Ice and Salt Hydrate Far Below the Original Melting Point by Mixing Alcohol: Crystal Structure Determination of Magnesium Chloride Heptahydrate

2020 ◽  
Author(s):  
Keishiro Yamashita ◽  
Kazuki Komatsu ◽  
Hiroyuki Kagi
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
Crystal Growth ◽  
Single Crystal ◽  
Room Temperature ◽  
Growth Technique ◽  
Salt Hydrate ◽  
X Ray

An crystal-growth technique for single crystal x-ray structure analysis of high-pressure forms of hydrogen-bonded crystals is proposed. We used alcohol mixture (methanol: ethanol = 4:1 in volumetric ratio), which is a widely used pressure transmitting medium, inhibiting the nucleation and growth of unwanted crystals. In this paper, two kinds of single crystals which have not been obtained using a conventional experimental technique were obtained using this technique: ice VI at 1.99 GPa and MgCl<sub>2</sub>·7H<sub>2</sub>O at 2.50 GPa at room temperature. Here we first report the crystal structure of MgCl2·7H2O. This technique simultaneously meets the requirement of hydrostaticity for high-pressure experiments and has feasibility for further in-situ measurements.

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