ChemInform Abstract: A SYNTHETIC APPLICATION OF METHYLTHIOACETONITRILE. I. A SYNTHESIS OF CIS- AND D TRANS-β-ARYLACRYLONITRILES, β,Γ-UNSATURATED NITRILES AND CARBONYL COMPOUNDS

S. KANO; T. YOKOMMATSU; T. ONO; S. HIBINO; S. SHIBUYA

doi:10.1002/chin.197845162

ChemInform Abstract: A SYNTHETIC APPLICATION OF METHYLTHIOACETONITRILE. I. A SYNTHESIS OF CIS- AND D TRANS-β-ARYLACRYLONITRILES, β,Γ-UNSATURATED NITRILES AND CARBONYL COMPOUNDS

Chemischer Informationsdienst ◽

10.1002/chin.197845162 ◽

1978 ◽

Vol 9 (45) ◽

Author(s):

S. KANO ◽

T. YOKOMMATSU ◽

T. ONO ◽

S. HIBINO ◽

S. SHIBUYA

Keyword(s):

Carbonyl Compounds ◽

Synthetic Application

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A synthetic application of methylthioacetonitrile. I. A synthesis of cis- and trans-.BETA.-arylacrylonitriles, .BETA.,.GAMMA.-unsaturated nitriles and carbonyl compounds.

Chemical and Pharmaceutical Bulletin ◽

10.1248/cpb.26.1874 ◽

1978 ◽

Vol 26 (6) ◽

pp. 1874-1879 ◽

Cited By ~ 6

Author(s):

SHINZO KANO ◽

TSUTOMU YOKOMMATSU ◽

TOSHIHIRO ONO ◽

SATOSHI HIBINO ◽

SHIROSHI SHIBUYA

Keyword(s):

Carbonyl Compounds ◽

Cis And Trans ◽

Synthetic Application

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ChemInform Abstract: Synthetic Application of Elementoorganic Compounds of the Fifteenth and Sixteenth Groups. Part 94. Reaction of Allyl Bromide with Carbonyl Compounds Mediated by Tributylbismuthine.

ChemInform ◽

10.1002/chin.199144111 ◽

2010 ◽

Vol 22 (44) ◽

pp. no-no

Author(s):

Y.-Z. HUANG ◽

Y. LIAO

Keyword(s):

Carbonyl Compounds ◽

Allyl Bromide ◽

Synthetic Application

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ChemInform Abstract: Synthetic Application of Elementoorganic Compounds of the 15th and 16th Groups. Part 81. Reactions of Carbonyl Compounds with Benzyldibutyltelluronium Bromide Mediated by Different Strong Bases.

ChemInform ◽

10.1002/chin.199132118 ◽

2010 ◽

Vol 22 (32) ◽

pp. no-no

Author(s):

S.-W. LI ◽

Z.-L. ZHOU ◽

Y.-Z. HUANG ◽

L.-L. SHI

Keyword(s):

Carbonyl Compounds ◽

Synthetic Application

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ChemInform Abstract: A New Synthetic Application of 1,2-Benzodithiolium Cations: Synthesis of Aldehydes by 1-Carbon Homologation of Carbonyl Compounds.

ChemInform ◽

10.1002/chin.198722166 ◽

1987 ◽

Vol 18 (22) ◽

Author(s):

M. CERUTI ◽

I. DEGANI ◽

R. FOCHI

Keyword(s):

Carbonyl Compounds ◽

Synthetic Application

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ChemInform Abstract: Synthetic Application of Elementoorganic Compounds of 15th and 16th Groups. Part 102. Reactions of Diazocompounds with Carbonyl Compounds Mediated by Diorganyl Telluride and Catalytic Amount of CuI. Conversion of Aldehydes to Alkenes

ChemInform ◽

10.1002/chin.199349117 ◽

2010 ◽

Vol 24 (49) ◽

pp. no-no

Author(s):

Z.-L. ZHOU ◽

Y.-Z. HUANG ◽

L.-L. SHI

Keyword(s):

Carbonyl Compounds ◽

Catalytic Amount ◽

Synthetic Application

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A New Synthetic Application of 1,2-Benzodithiolium Cations: Synthesis of Aldehydes by 1-Carbon Homologation of Carbonyl Compounds

Synthesis ◽

10.1055/s-1987-27857 ◽

1987 ◽

Vol 1987 (01) ◽

pp. 79-82 ◽

Cited By ~ 13

Author(s):

Maurizio Ceruti ◽

Iacopo Degani ◽

Rita Fochi

Keyword(s):

Carbonyl Compounds ◽

Synthetic Application

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ChemInform Abstract: Synthetic Application of Elementoorganic Compounds of the 15th and 16th Groups. Part 92. Novel Reaction of Dibutyl(cyanomethyl) telluronium Chloride with Carbonyl Compounds Mediated by Organolithium Reagents: Highly Efficient Synthesi

ChemInform ◽

10.1002/chin.199145125 ◽

2010 ◽

Vol 22 (45) ◽

pp. no-no

Author(s):

Z.-L. ZHOU ◽

L.-L. SHI ◽

Y.-Z. HUANG

Keyword(s):

Carbonyl Compounds ◽

Highly Efficient ◽

Organolithium Reagents ◽

Synthetic Application

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The reduction of α,β-unsaturated carbonyl compounds by the meerwein—ponndorf—verley method: The cause of low yields

Journal of Applied Chemistry and Biotechnology ◽

10.1002/jctb.5020220404 ◽

1972 ◽

Vol 22 (4) ◽

pp. 465-474 ◽

Cited By ~ 2

Author(s):

J. H. P. Tyman

Keyword(s):

Carbonyl Compounds

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Silicon Assisted Sulfuration: Tetrachlorosilane-Sodium Sulfide-A New Potent Thionating Reagent for Carbonyl Compounds

10.3390/ecsoc-11-01317 ◽

2007 ◽

Author(s):

T. A. Salama ◽

S. S. Elmorsy ◽

A. M. Khalil ◽

M. A. Ismail ◽

A. S. El-Ahl

Keyword(s):

Carbonyl Compounds ◽

Sodium Sulfide

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A FACILE SYNTHESIS AND REACTIONS OF AMINO SELENOLO[2,3-b]PYRIDINE CARBOXYLATE

JOURNAL OF ADVANCES IN CHEMISTRY ◽

10.24297/jac.v12i1.845 ◽

2015 ◽

Vol 12 (1) ◽

pp. 3910-3918 ◽

Cited By ~ 1

Author(s):

Dr Remon M Zaki ◽

Prof Adel M. Kamal El-Dean ◽

Dr Nermin A Marzouk ◽

Prof Jehan A Micky ◽

Mrs Rasha H Ahmed

Keyword(s):

Biological Activity ◽

Carbonyl Compounds ◽

Mass Spectra ◽

The Other ◽

Pyridine Derivatives ◽

Facile Synthesis ◽

High Biological Activity ◽

Basic Hydrolysis ◽

Pyridine Carboxylate ◽

Hydrolysis Of

Incorporating selenium metal bonded to the pyridine nucleus was achieved by the reaction of selenium metal with 2-chloropyridine carbonitrile 1 in the presence of sodium borohydride as reducing agent. The resulting non isolated selanyl sodium salt was subjected to react with various α-halogenated carbonyl compounds to afford the selenyl pyridine derivatives 3a-f which compounds 3a-d underwent Thorpe-Ziegler cyclization to give 1-amino-2-substitutedselenolo[2,3-b]pyridine compounds 4a-d, while the other compounds 3e,f failed to be cyclized. Basic hydrolysis of amino selenolo[2,3-b]pyridine carboxylate 4a followed by decarboxylation furnished the corresponding amino selenolopyridine compound 6 which was used as a versatile precursor for synthesis of other heterocyclic compound 7-16. All the newly synthesized compounds were established by elemental and spectral analysis (IR, 1H NMR) in addition to mass spectra for some of them hoping these compounds afforded high biological activity.

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