ChemInform Abstract: DERIVATIVES OF BIVALENT GERMANIUM, TIN AND LEAD. PART XXII. PALLADIUM AND PLATINUM COMPLEXES OF BIVALENT TIN COMPOUNDS

1978 ◽  
Vol 9 (40) ◽  
Author(s):  
P. F. R. EWINGS ◽  
P. G. HARRISON
Keyword(s):  
Platinum Complexes ◽  
Tin Compounds ◽  
Germanium Tin ◽  
Palladium And Platinum Complexes ◽  
Derivatives Of

Thio derivatives of b-diketones and their metal chelates. XXII. Dipole moments of some bivalent and trivalent metal complexes of fluorinated monothio-b-diketones

1976 ◽  
Vol 29 (4) ◽  
pp. 767 ◽  
Author(s):  
M Das ◽  
SE Livingstone ◽  
JH Mayfield ◽  
DS Moore ◽  
N Saha
Keyword(s):  
Copper Complexes ◽  
Dipole Moments ◽  
Platinum Complexes ◽  
Mean Value ◽  
Tetrahedral Configuration ◽  
Square Planar ◽  
Palladium And Platinum Complexes ◽  
Static Polarization ◽  
The Moment ◽  
Derivatives Of

Dipole moments have been determined by static polarization measurements for some iron(111), ruthenium(111), rhodium(111), nickel(11), palladium(11), platinum(11), copper(11) and zinc(11) complexes of fluorinated monothio-β-diketones RC(SH)=CHCOCF3. The moments indicate a facial-octahedral configuration for the iron, ruthenium and rhodium complexes, a cis-square-planar configuration for the nickel, palladium and platinum complexes, and a tetrahedral configuration for the zinc complexes. The copper complexes have moments 0.5-1.0 D lower than the mean value for the corresponding nickel, palladium and platinum complexes; this lowering of the moment is attributed to significant distortion from the square-planar towards the tetrahedral configuration. The dipole moments of the square-planar and octahedral complexes decrease if the R groups are arranged in the order: p-MeC6H4 ≥ 2-thienyl > β-naphthyl > m-MeC6H4 > Ph > Pr? > Bui > Me > m-ClC6H4 > m-BrC6H4 > p-FC6H4 > p-ClC6H4 > p-BrC6H4 > m,p-Cl2C6H3.

Synthesis and Characterization of Methyl-Palladium and -Platinum Complexes Supported by N,O- and N,S-Donor Ligands

2016 ◽  
Vol 2016 (6) ◽  
pp. 874-879 ◽  
Author(s):  
Daniel Ruiz Plaza ◽  
José C. Alvarado-Monzón ◽  
Gabriel A. Andreu de Riquer ◽  
Gerardo González-García ◽  
Herbert Höpfl ◽  
...  
Keyword(s):  
Platinum Complexes ◽  
Donor Ligands ◽  
Synthesis And Characterization ◽  
Palladium And Platinum Complexes

Dipyrrin based luminescent cyclometallated palladium and platinum complexes

2010 ◽  
Vol 39 (1) ◽  
pp. 180-184 ◽  
Author(s):  
Catherine Bronner ◽  
Stéphane A. Baudron ◽  
Mir Wais Hosseini ◽  
Cristian A. Strassert ◽  
Aurélie Guenet ◽  
...  
Keyword(s):  
Platinum Complexes ◽  
Palladium And Platinum Complexes
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