ChemInform Abstract: AQUEOUS LANTHANIDE SHIFT REAGENTS. 6. LANTHANIDE EFFECTS ON THE PROTON AND CARBON-13 RELAXATION RATES OF SARCOSINE. EVIDENCE FOR ISOSTRUCTURAL AMINO ACID COMPLEXES ALONG THE LANTHANIDE SERIES

G. A. ELGAVISH; J. REUBEN

doi:10.1002/chin.197836056

ChemInform Abstract: AQUEOUS LANTHANIDE SHIFT REAGENTS. 6. LANTHANIDE EFFECTS ON THE PROTON AND CARBON-13 RELAXATION RATES OF SARCOSINE. EVIDENCE FOR ISOSTRUCTURAL AMINO ACID COMPLEXES ALONG THE LANTHANIDE SERIES

Chemischer Informationsdienst ◽

10.1002/chin.197836056 ◽

1978 ◽

Vol 9 (36) ◽

Author(s):

G. A. ELGAVISH ◽

J. REUBEN

Keyword(s):

Amino Acid ◽

Relaxation Rates ◽

Amino Acid Complexes ◽

Lanthanide Series ◽

Lanthanide Shift Reagents ◽

Shift Reagents

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Aqueous lanthanide shift reagents. 6. Lanthanide effects on the proton and carbon-13 relaxation rates of sarcosine. Evidence for isostructural amino acid complexes along the lanthanide series

Journal of the American Chemical Society ◽

10.1021/ja00479a065 ◽

1978 ◽

Vol 100 (11) ◽

pp. 3617-3619 ◽

Cited By ~ 21

Author(s):

Gabriel A. Elgavish ◽

Jacques Reuben

Keyword(s):

Amino Acid ◽

Relaxation Rates ◽

Amino Acid Complexes ◽

Lanthanide Series ◽

Lanthanide Shift Reagents ◽

Shift Reagents

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Europium(III)-N,N′-Ethylenebis(L-amino acid) Complexes as New Chiral NMR Lanthanide Shift Reagents for Unprotectedα-Amino Acids in Neutral Aqueous Solution

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.74.707 ◽

2001 ◽

Vol 74 (4) ◽

pp. 707-715 ◽

Cited By ~ 12

Author(s):

Makoto Takemura ◽

Kazuhiro Yamato ◽

Matsumi Doe ◽

Masaaki Watanabe ◽

Hiroyuki Miyake ◽

...

Keyword(s):

Aqueous Solution ◽

Amino Acids ◽

Amino Acid ◽

Amino Acid Complexes ◽

Neutral Aqueous Solution ◽

Lanthanide Shift Reagents ◽

Shift Reagents

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ChemInform Abstract: Europium(III)-N,N′-ethylenebis(L-amino acid) Complexes as New Chiral NMR Lanthanoid Shift Reagents for Unprotected α-Amino Acids in Neutral Aqueous Solution.

ChemInform ◽

10.1002/chin.200128030 ◽

2010 ◽

Vol 32 (28) ◽

pp. no-no

Author(s):

Makoto Takemura ◽

Kazuhiro Yamato ◽

Matsumi Doe ◽

Masaaki Watanabe ◽

Hiroyuki Miyake ◽

...

Keyword(s):

Aqueous Solution ◽

Amino Acids ◽

Amino Acid ◽

Amino Acid Complexes ◽

Neutral Aqueous Solution ◽

Shift Reagents

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Conformation of protected amino acids. V. Application of lanthanide-shift reagents for conformational studies of tert-butoxycarbonyl .alpha.-amino acid esters: equilibrium changes and kinetics of the isomerization

Journal of the American Chemical Society ◽

10.1021/ja00435a032 ◽

1976 ◽

Vol 98 (19) ◽

pp. 5969-5973 ◽

Cited By ~ 24

Author(s):

Horst Kessler ◽

Michael Molter

Keyword(s):

Amino Acids ◽

Amino Acid ◽

Amino Acid Esters ◽

Conformational Studies ◽

Lanthanide Shift Reagents ◽

Shift Reagents ◽

Kinetics Of ◽

Alpha Amino Acid ◽

Acid Esters

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ChemInform Abstract: CONFORMATION OF PROTECTED AMINO ACIDS. V. APPLICATION OF LANTHANIDE-SHIFT REAGENTS FOR CONFORMATIONAL STUDIES OF TERT-BUTOXYCARBONYL α-AMINO ACID ESTERS- EQUILIBRIUM CHANGES AND KINETICS OF THE ISOMERIZATION

Chemischer Informationsdienst ◽

10.1002/chin.197650065 ◽

1976 ◽

Vol 7 (50) ◽

Author(s):

H. KESSLER ◽

M. MOLTER

Keyword(s):

Amino Acids ◽

Amino Acid ◽

Amino Acid Esters ◽

Conformational Studies ◽

Lanthanide Shift Reagents ◽

Shift Reagents ◽

Kinetics Of ◽

Acid Esters

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Lanthanide Shift Reagents. XV. Quantitation of D, L-Amino Acid Enantiomers Using Chiral Lanthanide Shift Reagents

Spectroscopy Letters ◽

10.1080/00387018008065097 ◽

1980 ◽

Vol 13 (5) ◽

pp. 321-327 ◽

Cited By ~ 13

Author(s):

David M. Rackham

Keyword(s):

Amino Acid ◽

Amino Acid Enantiomers ◽

Lanthanide Shift Reagents ◽

Shift Reagents

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Potentiometric study of enantioselective effects in α-amino acid complexes of copper(II)

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)83787-1 ◽

1985 ◽

Vol 104 (1) ◽

pp. 63-67 ◽

Cited By ~ 6

Author(s):

I.L. Ulanovski ◽

A.A. Kurganov ◽

V.A. Davankov

Keyword(s):

Amino Acid ◽

Potentiometric Study ◽

Amino Acid Complexes

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Lanthanide Shift Reagents XI1,2Equilibrium Constants for Phenyl Carbinols and Fluorenols

Spectroscopy Letters ◽

10.1080/00387017908063475 ◽

1979 ◽

Vol 12 (1) ◽

pp. 17-23 ◽

Cited By ~ 8

Author(s):

David M. Rackham ◽

Joyce Binks

Keyword(s):

Lanthanide Shift Reagents ◽

Shift Reagents

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Synthesis, Characterization, and Non-Covalent Interactions of Palladium(II)-Amino Acid Complexes

Molecules ◽

10.3390/molecules26144331 ◽

2021 ◽

Vol 26 (14) ◽

pp. 4331

Author(s):

David B. Hobart ◽

Michael A. G. Berg ◽

Hannah M. Rogers ◽

Joseph S. Merola

Keyword(s):

Amino Acid ◽

High Resolution Mass Spectrometry ◽

Resonance Spectroscopy ◽

Spectroscopic Techniques ◽

X Ray Diffraction ◽

Amino Acid Complexes ◽

Acetone Water ◽

Square Planar ◽

Non Covalent Interactions ◽

Covalent Interactions

The reaction of palladium(II) acetate with acyclic amino acids in acetone/water yields square planar bis-chelated palladium amino acid complexes that exhibit interesting non-covalent interactions. In all cases, complexes were examined by multiple spectroscopic techniques, especially HRMS (high resolution mass spectrometry), IR (infrared spectroscopy), and 1H NMR (nuclear magnetic resonance) spectroscopy. In some cases, suitable crystals for single crystal X-ray diffraction were able to be grown and the molecular structure was obtained. The molecular geometries of the products are discussed. Except for the alanine complex, all complexes incorporate water molecules into the extended lattice and exhibit N-H···O and/or O···(HOH)···O hydrogen bonding interactions. The non-covalent interactions are discussed in terms of the extended lattice structures exhibited by the structures.

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