ChemInform Abstract: ALKYL GROUP ISOMERIZATION IN THE OXIDATIVE ADDITION OF ACYL CHLORIDES TO IRIDIUM(I) COMPLEXES

1978 ◽  
Vol 9 (33) ◽  
Author(s):  
M. A. BENNETT ◽  
R. CHARLES ◽  
T. R. B. MITCHELL
Keyword(s):  
Alkyl Group ◽  
Oxidative Addition ◽  
Acyl Chlorides

Alkyl group isomerization in the oxidative addition of acyl chlorides to iridium(I) complexes

1978 ◽  
Vol 100 (9) ◽  
pp. 2737-2743 ◽  
Author(s):  
M. A. Bennett ◽  
R. Charles ◽  
T. R. B. Mitchell
Keyword(s):  
Alkyl Group ◽  
Oxidative Addition ◽  
Acyl Chlorides

Organoplatinum(IV) complexes with functional alkyl groups and their use in supramolecular chemistry

2009 ◽  
Vol 87 (7) ◽  
pp. 904-916 ◽  
Author(s):  
Richard H.W. Au ◽  
Lisa J. Findlay-Shirras ◽  
Neil M. Woody ◽  
Michael C. Jennings ◽  
Richard J. Puddephatt
Keyword(s):  
Supramolecular Chemistry ◽  
Self Assembly ◽  
Alkyl Group ◽  
Oxidative Addition ◽  
Alkyl Groups ◽  
Alkyl Bromides ◽  
Diimine Ligand

The oxidative addition of alkyl bromides RCH2Br (R = C5H4N, C6H4CN, CH2C6H4CO2H, or CH2C6H4CH2CO2H) to dimethylplatinum(II) complexes [PtMe2(LL)] (LL = diimine ligand) gives the corresponding organoplatinum(IV) complexes [PtBrMe2(CH2R)(LL)] containing functionality in the alkyl group RCH2. The pyridyl derivatives can be protonated, while abstraction of the bromide ligand from [PtBrMe2(CH2R)(LL)] can form cationic complexes, which can react with water or form oligomers by self-assembly.

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