ChemInform Abstract: NONEQUIVALENCE IN NO-DIALKYL-N-ARALKYLHYDROXYLAMINES- NITROGEN-OXYGEN BOND ROTATION VERSUS NITROGEN INVERSION CONTROVERSY

1978 ◽  
Vol 9 (31) ◽  
Author(s):  
T. B. POSNER ◽  
D. A. COUCH ◽  
C. D. HALL
Keyword(s):  
Bond Rotation ◽  
Nitrogen Inversion ◽  
Oxygen Bond

Nitrogen inversion and N–O bond rotation in some hydroxylamine and isoxazolidine derivatives

1997 ◽  
pp. 411-418 ◽  
Author(s):  
Azfar Hassan ◽  
Mohamed I. M. Wazeer ◽  
Herman P. Perzanowski ◽  
Sk. Asrof Ali
Keyword(s):  
Bond Rotation ◽  
Nitrogen Inversion

Photoinduced Sulfur–Nitrogen Bond Rotation and Thermal Nitrogen Inversion in Heterocumulene OSNSO

2018 ◽  
Vol 140 (4) ◽  
pp. 1231-1234 ◽  
Author(s):  
Zhuang Wu ◽  
Ruijuan Feng ◽  
Jian Xu ◽  
Yan Lu ◽  
Bo Lu ◽  
...  
Keyword(s):  
Bond Rotation ◽  
Nitrogen Inversion ◽  
Nitrogen Bond

ChemInform Abstract: Nitrogen Inversion and N-O Bond Rotation in Some Hydroxylamine and Isoxazolidine Derivatives

ChemInform ◽  
2010 ◽  
Vol 28 (27) ◽  
pp. no-no
Author(s):  
A. HASSAN ◽  
M. I. M. WAZEER ◽  
H. P. PERZANOWSKI ◽  
SK. A. ALI
Keyword(s):  
Bond Rotation ◽  
Nitrogen Inversion

Oxygen-Oxygen Bond Cleavage and Formation in Co(II) Mediated Stoichiometric O2 Reduction via the Potential Intermediacy of a Co(IV) Oxyl Radical

2018 ◽  
Author(s):  
Lucie Nurdin ◽  
Denis M. Spasyuk ◽  
Laura Fairburn ◽  
Warren Piers ◽  
Laurent Maron
Keyword(s):  
Bond Cleavage ◽  
Peroxo Complex ◽  
Oxygen Oxygen ◽  
O2 Reduction ◽  
Oxygen Bond ◽  
Pentadentate Ligand

Diprotonation of a remarkably stable, toluene soluble cobalt peroxo complex supported by a neutral, dianionic pentadentate ligand leads to facile O-O bond cleavage and production of a highly reactive Co(IV) oxyl cation intermediate that dimerizes and releases O<sub>2</sub>. These processes are relevant to both O<sub>2</sub> reduction and O<sub>2</sub> evolution and the mechanism was probed in detail both experimentally and computationally.

Formation of Carbon-Oxygen Bond Mediated by Hypervalent Iodine Reagents Under Metal-free Conditions

2020 ◽  
Vol 17 ◽  
Author(s):  
Ayesha Jalil ◽  
Yaxin O Yang ◽  
Zhendong Chen ◽  
Rongxuan Jia ◽  
Tianhao Bi ◽  
...  
Keyword(s):  
Natural Products ◽  
Bond Formation ◽  
Building Blocks ◽  
Review Article ◽  
Hypervalent Iodine ◽  
Metal Free ◽  
Bioactive Natural Products ◽  
The Past ◽  
Oxygen Bond ◽  
Privileged Scaffolds

: Hypervalent iodine reagents are a class of non-metallic oxidants have been widely used in the construction of several sorts of bond formations. This surging interest in hypervalent iodine reagents is essentially due to their very useful oxidizing properties, combined with their benign environmental character and commercial availability from the past few decades ago. Furthermore, these hypervalent iodine reagents have been used in the construction of many significant building blocks and privileged scaffolds of bioactive natural products. The purpose of writing this review article is to explore all the transformations in which carbon-oxygen bond formation occurred by using hypervalent iodine reagents under metal-free conditions

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