ChemInform Abstract: Stereochemistry of Nucleophilic Addition Reactions. Part 5. Formation of Stabilized Ylides from Methyl 4,6-O-Benzylidene-2,3-dideoxy-3-nitro-β-D-erythro-hex-2-enopyranoside with Some S-Ylides; an Important Role of the Nitro Group for

1978 ◽  
Vol 9 (29) ◽  
Author(s):  
T. SAKAKIBARA ◽  
R. SUDOH ◽  
T. NAKAGAWA
Keyword(s):  
Nitro Group ◽  
Nucleophilic Addition ◽  
Addition Reactions

scholarly journals Nucleophilic Addition Reactions of Nitriles to Nitrones under Mild Silylation Conditions

Synlett ◽  
2014 ◽  
Vol 25 (13) ◽  
pp. 1863-1868 ◽  
Author(s):  
Fumihiko Yoshimura ◽  
Keiji Tanino ◽  
Taiki Abe
Keyword(s):  
Nucleophilic Addition ◽  
Addition Reactions

Amide-Directed Reactions of Small Carbocycles

2021 ◽  
Vol 25 ◽  
Author(s):  
Pavel M. Yamanushkin ◽  
Marina Rubina ◽  
Michael Rubin
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Nucleophilic Addition ◽  
Addition Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

: The topic of this review is the amide-directed functionalization of strained carbocycles — specifically, unsaturated or saturated three- and four-membered rings. The following approaches are discussed: a) directed carbometallation and hydrometallation of cyclopropenes catalyzed by transition metals; b) directed metal-templated nucleophilic addition reactions; c) directed C-H functionalization, including transition metal-catalyzed C-H-activation reactions; and d) directed radical additions.

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