ChemInform Abstract: CRYSTAL AND MOLECULAR STRUCTURE OF TRIS(ETHYLENEDIAMINE)NICKEL(II) TETRAPHENYLBORATE-TRIS(DIMETHYL SULFOXIDE), (NI(NH2CH2CH2NH2)3)(B(C6H5)4)2.3(CH3)2SO. FACTORS INFLUENCING THE RING CONFORMATIONS IN TRIS(ETHYLENEDIAMINE) METAL COMPLEX

1978 ◽  
Vol 9 (21) ◽  
Author(s):  
R. E. CRAMER ◽  
J. T. HUNEKE
Keyword(s):  
Molecular Structure ◽  
Metal Complex ◽  
Dimethyl Sulfoxide ◽  
Crystal And Molecular Structure ◽  
Factors Influencing ◽  
Ring Conformations

scholarly journals Crystal and molecular structure of the binuclear Rh(I) complex (μ-Cl)(μ-pz) [Rh(CO)2]2 (pz = pyrazolyl, N2C3H3). An example of molecular stacking via weak intermolecular interactions

1985 ◽  
Vol 63 (3) ◽  
pp. 688-691 ◽  
Author(s):  
Brenda M. Louie ◽  
Steven J. Rettig ◽  
Alan Storr ◽  
James Trotter
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Physical Properties ◽  
Transition Metal Complex ◽  
Crystal And Molecular Structure ◽  
Heavy Atom ◽  
Full Matrix ◽  
Weak Intermolecular Interactions ◽  
Molecular Stacking

Details of the synthesis and physical properties of (μ-Cl)(μ-pz)[Rh(CO)2]2 are given. Crystals of (μ-chloro) (μ-pyrazolyl)-bis(dicarbonylrhodiumd(I)) are monoclinic, a = 7.0970(8), b = 20.5184(10), c = 15.808(2) Å, β = 94.695(6)°, Z = 8, space group P21/c. The structure was solved by conventional heavy-atom methods and was refined by full-matrix least-squares procedures to R = 0.035 and Rw = 0.038 for 2949 reflections with I ≥ 3σ(I). The complex provides a rare example of molecular stacking in a binuclear transition metal complex with [Formula: see text] distances of 3.5107(8) and 3.6201(8) Å.

Two independent determinations of the crystal and molecular structure oftrans-dichloro-bis(dimethyl sulfoxide)palladium(II)

1967 ◽  
Vol 23 (5) ◽  
pp. 788-796 ◽  
Author(s):  
M. J. Bennett ◽  
F. A. Cotton ◽  
D. L. Weaver ◽  
R. J. Williams ◽  
W. H. Watson
Keyword(s):  
Molecular Structure ◽  
Dimethyl Sulfoxide ◽  
Crystal And Molecular Structure

scholarly journals Crystal and Molecular Structure of Hexakis(dimethyl sulfoxide)cadmium(II) Perchlorate, [Cd((CH3)2SO)6](ClO4)2.

1978 ◽  
Vol 32a ◽  
pp. 519-525 ◽  
Author(s):  
Magnus Sandström ◽  
Markus Koskenlinna ◽  
Torben Smith Sørensen ◽  
Elina Näsäkkälä ◽  
Otto Bastiansen ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Dimethyl Sulfoxide ◽  
Crystal And Molecular Structure

Crystal and molecular structure of 1,2:3,4-Di-O-isopropylidene-6-O-toluene-p-sulfonyl-α-d-galactopyranose: Ring conformations in Di-O-isopropylidenegalactopyranose systems

1986 ◽  
Vol 148 (1) ◽  
pp. 1-11 ◽  
Author(s):  
Janusz W. Krajewski ◽  
Przemysa̵w Gluziński ◽  
Zofia Urbańczyk-Lipkowska ◽  
Aleksander Zamojski ◽  
Giovanni Dario Andreetti ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Ring Conformations

Metallkomplexe funktioneller Isocyanide, XIII Bis(oxazolidin-2-yliden)-Komplexe von Mangan(I) und Nickel(II) / Metal Complexes of Functional Isocyanides, XIII Bis(oxazolidin-2-ylidene) Complexes of Manganese(I) and Nickel(II)

1986 ◽  
Vol 41 (8) ◽  
pp. 1005-1010 ◽  
Author(s):  
Wolf Peter Fehlhammer ◽  
Ulrike Plaia
Keyword(s):  
Molecular Structure ◽  
Hydrogen Bonding ◽  
Metal Complexes ◽  
Crystal And Molecular Structure ◽  
Metal Carbonyl ◽  
Bonding Parameters ◽  
Factors Influencing

AbstractThe dicarbene complexes, MnBr(CO)3 [xxx] (1) and [xxx] (2), are synthesized from metal carbonyl precursors and CNCH2CH2OH . Factors influencing this 2-hydroxyalkyl isocyanide → N ,O-carbene isomerization are discussed. The crystal and molecular structure of 2 shows a distorted trigonal geometry about the central Ni atom. Extensive hydrogen bonding ((N )H ··· F 2.09, 2.38 Å ) occurs between cations and anions giving rise to infinite chains. Other pertinent bonding parameters are Ni-C (carbene) 1.860(4), 1.864(4) Å; C(carbene) [xxx] N 1.309(6), 1.304(6) Å , and C - Ni - C 97.7(2)°.

Crystal and molecular structure of a new biguanide metal complex, [Cu(AMNH)2]Cl2

1993 ◽  
Vol 23 (6) ◽  
pp. 509-512 ◽  
Author(s):  
Bankim C. Das ◽  
I. Dey ◽  
G. Biswas ◽  
R. Banerjee ◽  
Y. Iitaka ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Metal Complex ◽  
Crystal And Molecular Structure
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