ChemInform Abstract: THE BORATOBIS(DIMETHYLPHOSPHONIOMETHYLIDE) ANION, A NEW TYPE OF LIGAND SYSTEM FOR ORGANOMETALLIC COMPOUNDS

1978 ◽  
Vol 9 (18) ◽  
Author(s):  
H. SCHMIDBAUR ◽  
G. MUELLER ◽  
U. SCHUBERT ◽  
O. ORAMA
Keyword(s):  
Organometallic Compounds ◽  
Ligand System ◽  
New Type

scholarly journals Organometallic Compounds of the Lanthanides 182 [1]. Calcium and Neodymium Complexes Containing the dpp-BIAN Ligand System: Synthesis and Molecular Structure of [(dpp-BIAN)CaI(THF)2]2 and [(dpp-BIAN)NdCl(THF)2]2

2007 ◽  
Vol 62 (9) ◽  
pp. 1107-1111 ◽  
Author(s):  
Herbert Schumann ◽  
Markus Hummert ◽  
Anton N. Lukoyanov ◽  
Valentina A. Chudakova ◽  
Igor L. Fedushkin
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Single Crystal ◽  
Radical Anion ◽  
Organometallic Compounds ◽  
Single Crystal Structure ◽  
System Synthesis ◽  
X Ray ◽  
Ligand System ◽  
Metal Atoms

Oxydation of (dpp-BIAN)Ca(THF)4 with 0.5 equiv. of I2 in THF yields [(dpp-BIAN)CaI(THF)2]2 (1). A corresponding neodymium compound [(dpp-BIAN)NdCl(THF)2]2 (2) has been obtained by reaction of (dpp-BIAN)Na2 with NdCl3 in THF. The X-ray single crystal structure analyses show 1 and 2 to be isostructural dimers containing octahedrally coordinated metal atoms bridged by the respective halides. The chelating dpp-BIAN ligand acts as a radical anion in the Ca2+ complex 1 and as a dianion in the Nd3+ complex 2, respectively.

The Boratobis(dimethylphosphiniomethylide) Anion, a Novel Ligand System for Organometallic Compounds

1978 ◽  
Vol 17 (2) ◽  
pp. 126-127 ◽  
Author(s):  
Hubert Schmidbaur ◽  
Gerhard Müller ◽  
Ulrich Schubert ◽  
Olli Orama
Keyword(s):  
Organometallic Compounds ◽  
Ligand System

Darstellung und Eigenschaften der Tris-(4-dimethylamino-phenyl)-arsen(V)- und -antimon(V)-Kationen / Synthesis and Properties of the Tris- (4-dimethylamino-phenyl) -Arsenic (V) - and -Antimony (V) -Cations

1972 ◽  
Vol 27 (6) ◽  
pp. 596-599 ◽  
Author(s):  
Jörn-Michael Keck ◽  
Günter Klar
Keyword(s):  
Electronic Structure ◽  
Coordination Number ◽  
Oxidation State ◽  
Crystal Violet ◽  
Organometallic Compounds ◽  
New Type

The synthesis of a new type of organometallic compounds with a group VB element and the composition Ar3E2+ (Ar = 4-dimethylamino-phenyl; E = As, Sb) in which this element has the oxidation state +5 and the coordination number 3 is reported. In accordance with the electronic and n.m.r. spectra it is assumed that the electronic structure of these intensive blue cations is similar to that of the isoelectronic cation of crystal violet.

The Microstructure of Shock-Synthesized Diamond

1967 ◽  
Vol 25 ◽  
pp. 324-325
Author(s):  
Lucien F. Trueb
Keyword(s):  
Single Crystals ◽  
Preferred Orientation ◽  
High Magnification ◽  
Texture Pattern ◽  
Shock Process ◽  
New Type ◽  
Diffraction Diagram

A new type of synthetic industrial diamond formed by an explosive shock process has been recently developed by the Du Pont Company. This material consists of a mixture of two basically different forms, as shown in Figure 1: relatively flat and compact aggregates of acicular crystallites, and single crystals in the form of irregular polyhedra with straight edges.Figure 2 is a high magnification micrograph typical for the fibrous aggregates; it shows that they are composed of bundles of crystallites 0.05-0.3 μ long and 0.02 μ. wide. The selected area diffraction diagram (insert in Figure 2) consists of a weak polycrystalline ring pattern and a strong texture pattern with arc reflections. The latter results from crystals having preferred orientation, which shows that in a given particle most fibrils have a similar orientation.

New type electron gun with electrostatic and electromagnetic lenses

1978 ◽  
Vol 36 (1) ◽  
pp. 62-63
Author(s):  
T. Ichinokawa ◽  
H. Maeda
Keyword(s):  
Electron Microscopy ◽  
Electron Beam ◽  
Optimum Condition ◽  
Bias Voltage ◽  
Electron Gun ◽  
Charge Effect ◽  
Micro Fabrication ◽  
Maximum Brightness ◽  
New Type ◽  
The Ideal

I. IntroductionThermionic electron gun with the Wehnelt grid is popularly used in the electron microscopy and electron beam micro-fabrication. It is well known that this gun could get the ideal brightness caluculated from the Lengumier and Richardson equations under the optimum condition. However, the design and ajustment to the optimum condition is not so easy. The gun has following properties with respect to the Wehnelt bias; (1) The maximum brightness is got only in the optimum bias. (2) In the larger bias than the optimum, the brightness decreases with increasing the bias voltage on account of the space charge effect. (3) In the smaller bias than the optimum, the brightness decreases with bias voltage on account of spreading of the cross over spot due to the aberrations of the electrostatic immersion lens.In the present experiment, a new type electron gun with the electrostatic and electromagnetic lens is designed, and its properties are examined experimentally.

A new type of defect structure in 124-superconducting oxide revealed by HREM

1991 ◽  
Vol 49 ◽  
pp. 1092-1093
Author(s):  
R. Sharma ◽  
B.L. Ramakrishna ◽  
N.N. Thadhani ◽  
D. Hianes ◽  
Z. Iqbal
Keyword(s):  
Shock Wave ◽  
Defect Structure ◽  
Neutron Radiation ◽  
Weak Links ◽  
Defect Structures ◽  
New Materials ◽  
New Type ◽  
Current Densities ◽  
Processing Techniques ◽  
Microstructural Studies

After materials with superconducting temperatures higher than liquid nitrogen have been prepared, more emphasis has been on increasing the current densities (Jc) of high Tc superconductors than finding new materials with higher transition temperatures. Different processing techniques i.e thin films, shock wave processing, neutron radiation etc. have been applied in order to increase Jc. Microstructural studies of compounds thus prepared have shown either a decrease in gram boundaries that act as weak-links or increase in defect structure that act as flux-pinning centers. We have studied shock wave synthesized Tl-Ba-Cu-O and shock wave processed Y-123 superconductors with somewhat different properties compared to those prepared by solid-state reaction. Here we report the defect structures observed in the shock-processed Y-124 superconductors.

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