ChemInform Abstract: COENZYME B12 MODEL STUDIES- THERMODYNAMICS AND KINETICS OF AXIAL LIGATION OF SUBSTITUTED ALKYL(AQUO)COBALOXIMES BY DIMETHOXYETHYLAMINE

K. L. BROWN; A. W. AWTREY

doi:10.1002/chin.197815312

ChemInform Abstract: COENZYME B12 MODEL STUDIES- THERMODYNAMICS AND KINETICS OF AXIAL LIGATION OF SUBSTITUTED ALKYL(AQUO)COBALOXIMES BY DIMETHOXYETHYLAMINE

Chemischer Informationsdienst ◽

10.1002/chin.197815312 ◽

1978 ◽

Vol 9 (15) ◽

Author(s):

K. L. BROWN ◽

A. W. AWTREY

Keyword(s):

Coenzyme B12 ◽

Model Studies ◽

Axial Ligation ◽

Thermodynamics And Kinetics ◽

Kinetics Of

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Coenzyme B12 model studies: thermodynamics and kinetics of axial ligation of substituted alkyl(aquo)cobaloximes by dimethoxyethylamine

Inorganic Chemistry ◽

10.1021/ic50179a024 ◽

1978 ◽

Vol 17 (1) ◽

pp. 111-119 ◽

Cited By ~ 26

Author(s):

Kenneth L. Brown ◽

Allan W. Awtrey

Keyword(s):

Coenzyme B12 ◽

Model Studies ◽

Axial Ligation ◽

Thermodynamics And Kinetics ◽

Kinetics Of

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Coenzyme B12 Model Studies− Kinetics of Axial Ligation of Alkylcobalt Complexes Containing a Tridentate Amino-Oximate Ligand

European Journal of Inorganic Chemistry ◽

10.1002/ejic.200300206 ◽

2003 ◽

Vol 2003 (20) ◽

pp. 3738-3744 ◽

Cited By ~ 5

Author(s):

Basam M. Alzoubi ◽

Mohamed S. A. Hamza ◽

Alessandro Felluga ◽

Lucio Randaccio ◽

Giovanni Tauzher ◽

...

Keyword(s):

Coenzyme B12 ◽

Model Studies ◽

Axial Ligation ◽

Kinetics Of

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Coenzyme B12 model studies. Equilibriums and kinetics of axial ligation of methylaquocobaloxime by thiols

Journal of the American Chemical Society ◽

10.1021/ja00761a018 ◽

1972 ◽

Vol 94 (6) ◽

pp. 1894-1901 ◽

Cited By ~ 43

Author(s):

Kenneth L. Brown ◽

Roland G. Kallen

Keyword(s):

Coenzyme B12 ◽

Model Studies ◽

Axial Ligation ◽

Kinetics Of

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Coenzyme B12 model studies: An HSAB approach to the equilibria and kinetics of axial ligation of alkyl(aquo)-cobaloximes by imidazole and cyanide

Journal of Chemical Sciences ◽

10.1007/bf02704365 ◽

2000 ◽

Vol 112 (6) ◽

pp. 579-591 ◽

Cited By ~ 8

Author(s):

Vaddeboina Sridhar ◽

S Satyanarayana

Keyword(s):

Coenzyme B12 ◽

Model Studies ◽

Axial Ligation ◽

Kinetics Of

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Coenzyme B12 model studies. Equilibriums and kinetics of axial ligation of methylaquocobaloxime by primary amines and 4-substituted pyridines

Journal of the American Chemical Society ◽

10.1021/ja00774a022 ◽

1972 ◽

Vol 94 (19) ◽

pp. 6697-6704 ◽

Cited By ~ 24

Author(s):

Kenneth L. Brown ◽

Donald Chernoff ◽

David J. Keljo ◽

Roland G. Kallen

Keyword(s):

Primary Amines ◽

Coenzyme B12 ◽

Model Studies ◽

Axial Ligation ◽

Substituted Pyridines ◽

Kinetics Of

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Coenzyme B12 model studies. Equilibriums and kinetics of axial ligation of substituted alkylcobaloximes by pyridine in aqueous solution

Journal of the American Chemical Society ◽

10.1021/ja00858a022 ◽

1975 ◽

Vol 97 (25) ◽

pp. 7338-7346 ◽

Cited By ~ 49

Author(s):

Kenneth L. Brown ◽

Douglas Lyles ◽

Michael Pencovici ◽

Roland G. Kallen

Keyword(s):

Aqueous Solution ◽

Coenzyme B12 ◽

Model Studies ◽

Axial Ligation ◽

Kinetics Of

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Coenzyme B12 model studies: Equilibrium constants for the pH-dependent axial ligation of benzyl(aquo)cobaloxime by various N- and S-donor ligands

Journal of Chemical Sciences ◽

10.1007/bf02709976 ◽

2002 ◽

Vol 114 (1) ◽

pp. 1-10 ◽

Cited By ~ 5

Author(s):

D. Sudarshan Reddy ◽

N. Ravi Kumar Reddy ◽

V. Sridhar ◽

S. Satyanarayana

Keyword(s):

Equilibrium Constants ◽

Donor Ligands ◽

Coenzyme B12 ◽

Model Studies ◽

Axial Ligation ◽

Ph Dependent

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Irradiation behavior of pyrolytic silicon carbide

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100074288 ◽

1983 ◽

Vol 41 ◽

pp. 72-73

Author(s):

R. J. Lauf

Keyword(s):

Silicon Carbide ◽

Fission Products ◽

Thermodynamics And Kinetics ◽

Neutron Fluences ◽

Fuel Particles ◽

Sic Coatings ◽

Irradiation Behavior ◽

Kinetics Of ◽

Htgr Fuel

Fuel particles for the High-Temperature Gas-Cooled Reactor (HTGR) contain a layer of pyrolytic silicon carbide to act as a miniature pressure vessel and primary fission product barrier. Optimization of the SiC with respect to fuel performance involves four areas of study: (a) characterization of as-deposited SiC coatings; (b) thermodynamics and kinetics of chemical reactions between SiC and fission products; (c) irradiation behavior of SiC in the absence of fission products; and (d) combined effects of irradiation and fission products. This paper reports the behavior of SiC deposited on inert microspheres and irradiated to fast neutron fluences typical of HTGR fuel at end-of-life.

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