ChemInform Abstract: EFFECT OF μ-SULFIDO LIGANDS ON SUBSTITUTION AT MOLYBDENUM(V). A TEMPERATURE-JUMP STUDY OF THE 1-1 EQUILIBRATION OF THIOCYANATE WITH DI-μ-SULFIDO-BIS(AQUOOXALATOOXOMOLYBDENUM(V))

1978 ◽  
Vol 9 (15) ◽  
Author(s):  
F. A. ARMSTRONG ◽  
T. SHIBAHARA ◽  
A. G. SYKES
Keyword(s):  
Author(s):  
T. Wichertjes ◽  
E.J. Kwak ◽  
E.F.J. Van Bruggen

Hemocyanin of the horseshoe crab (Limulus polyphemus) has been studied in nany ways. Recently the structure, dissociation and reassembly was studied using electron microscopy of negatively stained specimens as the method of investigation. Crystallization of the protein proved to be possible and X-ray crystallographic analysis was started. Also fluorescence properties of the hemocyanin after dialysis against Tris-glycine buffer + 0.01 M EDTA pH 8.9 (so called “stripped” hemocyanin) and its fractions II and V were studied, as well as functional properties of the fractions by NMR. Finally the temperature-jump method was used for assaying the oxygen binding of the dissociating molecule and of preparations of isolated subunits. Nevertheless very little is known about the structure of the intact molecule. Schutter et al. suggested that the molecule possibly consists of two halves, combined in a staggered way, the halves themselves consisting of four subunits arranged in a square.


1990 ◽  
Vol 61 (1) ◽  
pp. 66-68 ◽  
Author(s):  
Kazuyuki Akasaka ◽  
Akira Naito ◽  
Hiroshi Nakatani ◽  
Mamoru Imanari

1988 ◽  
Vol 263 (21) ◽  
pp. 10344-10352
Author(s):  
M Caplow ◽  
J Shanks ◽  
R L Ruhlen

1966 ◽  
Vol 241 (11) ◽  
pp. 2653-2660
Author(s):  
Douglas E. Goldsack ◽  
Wolfgang S. Eberlein ◽  
Robert A. Alberty
Keyword(s):  

2016 ◽  
Vol 20 (5) ◽  
pp. 1585-1596 ◽  
Author(s):  
Jamalabadia Abdollahzadeh ◽  
Hyun Park ◽  
Chang Lee

This study presents the effect of thermal radiation on the steady flow in a vertical micro channel filled with highly absorbing medium. The governing equations (mass, momentum and energy equation with Rosseland approximation and slip boundary condition) are solved analytically. The effects of thermal radiation parameter, the temperature parameter, Reynolds number, Grashof number, velocity slip length, and temperature jump on the velocity and temperature profiles, Nusselt number, and skin friction coefficient are investigated. Results show that the skin friction and the Nusselt number are increased with increase in Grashof number, velocity slip, and pressure gradient while temperature jump and Reynolds number have an adverse effect on them. Furthermore, a criterion for the flow unsteadiness based on the temperature parameter, thermal radiation parameter, and the temperature jump is presented.


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