ChemInform Abstract: NEGATIVE ION CHEMISTRY OF (η5-CYCLOPENTADIENYL)DICARBONYLCOBALT IN THE GAS PHASE BY ION CYCLOTRON RESONANCE SPECTROSCOPY. THE Π-ACCEPTOR ABILITY OF PHOSPHORUS TRIFLUORIDE COMPARED TO CARBON MONOXIDE

1978 ◽  
Vol 9 (11) ◽  
Author(s):  
R. R. CORDERMAN ◽  
J. L. BEAUCHAMP
Keyword(s):  
Carbon Monoxide ◽  
Gas Phase ◽  
Cyclotron Resonance ◽  
Negative Ion ◽  
Resonance Spectroscopy ◽  
Ion Cyclotron Resonance ◽  
Ion Chemistry ◽  
Ion Cyclotron

Bimolecular production of gas phase ionic hydrates by ion cyclotron resonance spectroscopy

1980 ◽  
Vol 58 (8) ◽  
pp. 863-865 ◽  
Author(s):  
R. L. Clair ◽  
T. B. McMahon
Keyword(s):  
Gas Phase ◽  
Cyclotron Resonance ◽  
Resonance Spectroscopy ◽  
Ion Cyclotron Resonance ◽  
Ion Chemistry ◽  
Ion Molecule Reactions ◽  
Hydronium Ion ◽  
Dominant Feature ◽  
Ion Cyclotron ◽  
Gas Phase Ion

The gas phase ion–molecule reactions of α,α,α′,α′ tetrafluorodimethyl ether both alone and in mixtures with water have been examined. The dominant feature of the ion chemistry of these mixtures is the sequential bimolecular production of the hydrated hydronium ion, H5O2+. Two independent mechanistic pathways for production of H5O2+ are outlined arising from reaction of H3O+ with (CF2H)2O and from CF2H—O=CHF+ with H2O. Implications for examination of solvent switching equilibria are discussed.

Sign in / Sign up

Export Citation Format

Share Document