scholarly journals Fine‐Tunable, Redox‐Active Octapalladium Chains Supported by Linear Tetraphosphines, Leading to Dynamically 1D Self‐Assembled Coordination Polymers

2021 ◽  
Author(s):  
Tomoaki Tanase ◽  
Kanako Nakamae ◽  
Haruka Miyano ◽  
Yasuyuki Ura ◽  
Yasutaka Kitagawa ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Redox Active ◽  
Self Assembled

scholarly journals Back Cover: Ferroelectric Coordination Polymers Self-Assembled from Mesogenic Zinc(II) Porphyrin and Dipolar Bridging Ligands (Chem. Eur. J. 40/2016)

2016 ◽  
Vol 22 (40) ◽  
pp. 14408-14408
Author(s):  
Joseph K.-H. Hui ◽  
Hiroyuki Kishida ◽  
Keita Ishiba ◽  
Kenta Takemasu ◽  
Masa-aki Morikawa ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Bridging Ligands ◽  
Back Cover ◽  
Self Assembled

Steric and Electronic Effects of Ligand Substitution on Redox-Active Fe4S4-Based Coordination Polymers

2021 ◽  
Author(s):  
Omar Salinas ◽  
Jiaze Xie ◽  
Robert Papoular ◽  
Noah Horwitz ◽  
Erik Elkaim ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Ligand Substitution ◽  
Molecular Materials ◽  
Electronic Effects ◽  
Redox Active ◽  
And Function ◽  
Structure Properties

One of the notable advantages of molecular materials is the ability to precisely tune structure, properties, and function via molecular substitutions. While many studies have demonstrated this principle with classic...

Exciton Coupling in Redox‐Active Salen based Self‐Assembled Metallacycles

2021 ◽  
Author(s):  
Khrystyna Herasymchuk ◽  
Magali Allain ◽  
Gregory A. MacNeil ◽  
Vincent Carré ◽  
Frédéric Aubriet ◽  
...  
Keyword(s):  
Exciton Coupling ◽  
Redox Active ◽  
Self Assembled

Redox-Triggered Folding of Self-Assembled Coordination Polymers incorporating Viologen Units

2018 ◽  
Vol 24 (49) ◽  
pp. 12961-12969 ◽  
Author(s):  
Wathiq Sattar Abdul-Hassan ◽  
Denis Roux ◽  
Christophe Bucher ◽  
Saioa Cobo ◽  
Florian Molton ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Self Assembled

scholarly journals Highly-organized stacked multilayers via layer-by-layer assembly of lipid-like surfactants and polyelectrolytes. Stratified supramolecular structures for (bio)electrochemical nanoarchitectonics

Soft Matter ◽  
2018 ◽  
Vol 14 (10) ◽  
pp. 1939-1952 ◽  
Author(s):  
M. Lorena Cortez ◽  
Agustín Lorenzo ◽  
Waldemar A. Marmisollé ◽  
Catalina von Bilderling ◽  
Eliana Maza ◽  
...  
Keyword(s):  
Supramolecular Structures ◽  
Layer By Layer ◽  
Layer By Layer Assembly ◽  
Redox Active ◽  
Self Assembled ◽  
Layer Assembly

Redox-active and (bio)functional hosts can be deliberately located in self-assembled stratified domains.

scholarly journals Redox-Active Monolayers Self-Assembled on Gold Electrodes—Effect of Their Structures on Electrochemical Parameters and DNA Sensing Ability

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 607 ◽  
Author(s):  
Kamila Malecka ◽  
Shalini Menon ◽  
Gopal Palla ◽  
Krishnapillai Girish Kumar ◽  
Mathias Daniels ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Redox Activity ◽  
Gold Electrodes ◽  
Complex Structures ◽  
Transfer Coefficients ◽  
Sensing Properties ◽  
Redox Active ◽  
Electrochemical Parameters ◽  
Self Assembled

The background: The monolayers self-assembled on the gold electrode incorporated transition metal complexes can act both as receptor (“host” molecules) immobilization sites, as well as transducer for interface recognitions of “guest” molecules present in the aqueous solutions. Their electrochemical parameters influencing the sensing properties strongly depend on the transition metal complex structures. The objectives: The electrochemical characterization of the symmetric terpyridine–M2+–terpyridine and asymmetric dipyrromethene–M2+–terpyridine complexes modified with ssDNA probe covalently attached to the gold electrodes and exploring their ssDNA sensing ability were the main aims of the research presented. The methods: Two transition metal cations have been selected: Cu2+ and Co2+ for creation of redox-active monolayers. The electron transfer coefficients indicating the reversibility and electron transfer rate constant measuring kinetic of redox reactions have been determined for all SAMs studied using: Cyclic Voltammetry, Osteryoung Square-Wave Voltammetry, and Differential Pulse Voltammetry. All redox-active platforms have been applied for immobilization of ssDNA probe. Next, their sensing properties towards complementary DNA target have been explored electrochemically. The results: All SAMs studied were stable displaying quasi-reversible redox activity. The linear relationships between cathodic and anodic current vs. san rate were obtained for both symmetric and asymmetric SAMs incorporating Co2+ and Cu2+, indicating that oxidized and reduced redox sites are adsorbed on the electrode surface. The ssDNA sensing ability were observed in the fM concentration range. The low responses towards non-complementary ssDNA sequences provided evidences for sensors good selectivity. The conclusions: All redox-active SAMs modified with a ssDNA probe were suitable for sensing of ssDNA target, with very good sensitivity in fM range and very good selectivity. The detection limits obtained for SAMs incorporating Cu2+, both symmetric and asymmetric, were better in comparison to SAMs incorporating Co2+. Thus, selection of the right transition metal cation has stronger influence on ssDNA sensing ability, than complex structures.

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