scholarly journals Thermally Activated Delayed Fluorescence from d 10 ‐Metal Carbene Complexes through Intermolecular Charge Transfer and Multicolor Emission with a Monomer–Dimer Equilibrium

2020 ◽  
Vol 26 (71) ◽  
pp. 17222-17229
Author(s):  
Lei Cao ◽  
Shiqing Huang ◽  
Wei Liu ◽  
Hongyan Zhao ◽  
Xiao‐Gen Xiong ◽  
...  
2020 ◽  
Vol 56 (63) ◽  
pp. 8988-8991
Author(s):  
Qingxin Liang ◽  
Jingyi Xu ◽  
Jie Xue ◽  
Juan Qiao

The first thermally activated delayed fluorescence emitter and organic light-emitting diodes in the near-infrared II region were realized via intermolecular charge-transfer aggregates.


Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1125
Author(s):  
Teng Teng ◽  
Jinfan Xiong ◽  
Gang Cheng ◽  
Changjiang Zhou ◽  
Xialei Lv ◽  
...  

A new series of tetrahedral heteroleptic copper(I) complexes exhibiting efficient thermally-activated delayed fluorescence (TADF) in green to orange electromagnetic spectral regions has been developed by using D-A type N^N ligand and P^P ligands. Their structures, electrochemical, photophysical, and electroluminescence properties have been characterized. The complexes exhibit high photoluminescence quantum yields (PLQYs) of up to 0.71 at room temperature in doped film and the lifetimes are in a wide range of 4.3–24.1 μs. Density functional theory (DFT) calculations on the complexes reveal the lowest-lying intraligand charge-transfer excited states that are localized on the N^N ligands. Solution-processed organic light emitting diodes (OLEDs) based on one of the new emitters show a maximum external quantum efficiency (EQE) of 7.96%.


Author(s):  
Kai Zhang ◽  
Jianzhong Fan ◽  
Chuankui Wang ◽  
Lili Lin

Modulating the relationship between molecular structures and luminescent properties as well as the charge transfer property for deep-red thermally activated delayed fluorescence (TADF) emitters has always been a powerful challenge,...


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