scholarly journals Ferrimagnetic Ordering and Anomalous Stoichiometry Observed for the Cubic, Extended 3D Prussian Blue Analogues (NEt 3 Me) 2 Mn II 5 (CN) 12 and (NEt 2 Me 2 ) 2 Mn II 5 (CN) 12 : A Cation‐Adaptive Structure

2020 ◽  
Vol 26 (67) ◽  
pp. 15565-15572
Author(s):  
Adora G. Graham ◽  
Saul H. Lapidus ◽  
Casey G. Hawkins ◽  
Peter W. Stephens ◽  
Joel S. Miller
Keyword(s):  
Prussian Blue ◽  
Prussian Blue Analogues ◽  
Adaptive Structure ◽  
Ferrimagnetic Ordering

Design and Synthesis of Concentration Gradient Prussian Blue Analogues

2021 ◽  
Vol 21 (2) ◽  
pp. 916-925
Author(s):  
SuKyung Jeon ◽  
Carissa H. Li ◽  
Daniel R. Talham
Keyword(s):  
Prussian Blue ◽  
Concentration Gradient ◽  
Design And Synthesis ◽  
Prussian Blue Analogues

Titelbild: Mesostructured Prussian Blue Analogues (Angew. Chem. 3/2008)

2007 ◽  
Vol 120 (3) ◽  
pp. 427-427
Author(s):  
Xavier Roy ◽  
Laurence K. Thompson ◽  
Neil Coombs ◽  
Mark J. MacLachlan
Keyword(s):  
Prussian Blue ◽  
Prussian Blue Analogues

scholarly journals “Green” Prussian Blue Analogues as Peroxidase Mimetics for Amperometric Sensing and Biosensing

Biosensors ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 193
Author(s):  
Galina Z. Gayda ◽  
Olha M. Demkiv ◽  
Yanna Gurianov ◽  
Roman Ya. Serkiz ◽  
Halyna M. Klepach ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Noble Metals ◽  
High Sensitivity ◽  
Graphite Electrodes ◽  
Flavocytochrome B2 ◽  
Prussian Blue Analogues ◽  
Scientific Investigations ◽  
Electrochemically Active ◽  
Amperometric Sensing ◽  
Prussian Blue Analogs

Prussian blue analogs (PBAs) are well-known artificial enzymes with peroxidase (PO)-like activity. PBAs have a high potential for applications in scientific investigations, industry, ecology and medicine. Being stable and both catalytically and electrochemically active, PBAs are promising in the construction of biosensors and biofuel cells. The “green” synthesis of PO-like PBAs using oxido-reductase flavocytochrome b2 is described in this study. When immobilized on graphite electrodes (GEs), the obtained green-synthesized PBAs or hexacyanoferrates (gHCFs) of transition and noble metals produced amperometric signals in response to H2O2. HCFs of copper, iron, palladium and other metals were synthesized and characterized by structure, size, catalytic properties and electro-mediator activities. The gCuHCF, as the most effective PO mimetic with a flower-like micro/nano superstructure, was used as an H2O2-sensitive platform for the development of a glucose oxidase (GO)-based biosensor. The GO/gCuHCF/GE biosensor exhibited high sensitivity (710 A M−1m−2), a broad linear range and good selectivity when tested on real samples of fruit juices. We propose that the gCuHCF and other gHCFs synthesized via enzymes may be used as artificial POs in amperometric oxidase-based (bio)sensors.

Bonding properties in Prussian blue analogues of the type Fe[Fe(CN)5X]·xH2O

1979 ◽  
Vol 41 (3) ◽  
pp. 287-292 ◽  
Author(s):  
E. Fluck ◽  
H. Inoue ◽  
M. Nagao ◽  
S. Yanagisawa
Keyword(s):  
Prussian Blue ◽  
Prussian Blue Analogues ◽  
Bonding Properties

Anomalous Stoichiometry, 3-D Bridged Triangular/Pentagonal Layered Structured Artificial Antiferromagnet for the Prussian Blue Analogue A3MnII5(CN)13(A = NMe4, NEtMe3). A Cation Adaptive Structure

2018 ◽  
Vol 141 (2) ◽  
pp. 911-921 ◽  
Author(s):  
Saul H. Lapidus ◽  
Adora G. Graham ◽  
Christopher M. Kareis ◽  
Casey G. Hawkins ◽  
Peter W. Stephens ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Prussian Blue Analogue ◽  
Adaptive Structure
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